A study on ligand-coupling reactions of imidoyl palladium complexes

Journal of Organometallic Chemistry

Volumn 692, Issue 1-3, 2007, Pages 620-624

  Morishita, Masashi ^a   Amii, Hideki ^a  

^a KOBE UNIVERSITY   (Japan)

Author keywords

Diimine; Insertion; Isocyanide; Ligand coupling; Oxidative addition; Palladium

Indexed keywords

COMPLEXATION; MOLECULAR STRUCTURE; ORGANOMETALLICS; REACTION KINETICS; TOLUENE;

DIIMINE; IMIDOYLPALLADIUM COMPLEXES; ISOCYANIDE; LIGAND COUPLING; OXIDATIVE ADDITION;

PALLADIUM COMPOUNDS;

EID: 33845655364     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.04.055     Document Type: Article

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37. n oligomers [Ref. [13h]] besides α-diimines.
38. 4-I (1 equiv) under the same conditions gave α-diimine 1d in 38% yield. In each experiment, the formation of the cross-coupling product 1g was not observed. These results suggest that the imidoyl-imidoyl coupling reactions would proceed via bimolecular ligand-exchange pathway.