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Volumn 36, Issue 16, 1997, Pages 1743-1745

Catalytic Three-Component Synthesis of Conjugated Dienes from Alkynes via Pd0, PdII, and PdIV Intermediates Containing 1,2-Diimine

Author keywords

C C coupling; Dienes; Multicomponent reactions; N ligands; Palladium

Indexed keywords


EID: 0030869219     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199717431     Document Type: Article
Times cited : (136)

References (42)
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    • a) E. Negishi in Comprehensive Organic Synthesis, Vol. 5 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, p. 1163;
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    • (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford
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    • (1991) Comprehensive Organic Synthesis , vol.4 , pp. 865
    • Knochel, P.1
  • 10
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    • Titanium and zirconium-catalyzed cyclization of diynes to exocyclic conjugated dienes: a) W. A. Nugent, J. C. Calabrese, J. Am. Chem. Soc. 1984, 106, 6422; b) E. Negishi, S. J. Holm, J. M. Tour, J. A. Miller, F. E. Cederbaum, D. R. Swanson, T. Takahashi, ibid. 1989, 111, 3336.
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 6422
    • Nugent, W.A.1    Calabrese, J.C.2
  • 13
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    • b) Tetrahedron 1994, 50, 323.
    • (1994) Tetrahedron , vol.50 , pp. 323
  • 18
    • 0642268481 scopus 로고    scopus 로고
    • note
    • Satisfactory spectral and analytical data were obtained for 2; the configurations around double bonds of the dienyl moiety were corroborated by an X-ray crystal structure determination (unpublished results).
  • 25
    • 0642360419 scopus 로고    scopus 로고
    • note
    • 2] with Ph-bip and dimethyl butynedioate to give 1. Inadvertant (partly) dissociated NN ligands may catalytically decompose DMF.
  • 26
    • 0642299159 scopus 로고    scopus 로고
    • note
    • 2Me)].
  • 30
    • 0642299158 scopus 로고    scopus 로고
    • note
    • 2-bian derivative), 2.93 and 3.65 ppm (Ph-bip derivative).
  • 31
    • 0642329732 scopus 로고    scopus 로고
    • note
    • 2 plane for 4).
  • 32
    • 0642299162 scopus 로고    scopus 로고
    • note
    • Satisfactory spectral and analytical data were obtained for 4; an X-ray crystal structure analysis of the iodo analogue of 4 (NN = bpy) was carried out (unpublished results).
  • 35
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    • b) B. M. Trost, A. S. K. Hashmi, Angew. Chem. 1993, 105, 1130; Angew. Chem. Int. Ed. Engl. 1993, 32, 1085;
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1085
  • 39
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    • d) M. Beller, H. Fischer, W. A. Herrmann, K. Öfele, C. Brossmer, ibid. 1995, 107, 1992 and 1995, 34, 1848;
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 1848
  • 42
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    • f) M. Catellani, F. Frignani, A. Rangoni, Angew. Chem. 1997, 109, 142; Angew. Chem. Int. Ed. Engl. 1997, 36, 119.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 119


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.