SmI2-induced reductive cyclization of (E)- and (Z)-β-alkoxyvinyl sulfones with aldehyde

Tetrahedron Letters

Volumn 48, Issue 1, 2007, Pages 43-46

  Kimura, Tomohiro ^a   Nakata, Tadashi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

C C Bond formation; Gymnocin A; Polycyclic ethers; Radical; Samarium diiodide

Indexed keywords

ALDEHYDE; ETHER DERIVATIVE; METHYL GROUP; SULFONE DERIVATIVE; TETRAHYDROPYRAN DERIVATIVE;

ARTICLE; CYCLIZATION; STEREOCHEMISTRY;

EID: 33751418358     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.11.030     Document Type: Article

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35. 3): δ 169.8, 140.3, 137.0, 133.7, 129.2, 128.8, 128.3, 128.1, 126.1, 101.9, 76.6, 76.4, 75.5, 74.9, 73.5, 68.9, 68.8, 58.0, 34.6, 34.0, 21.0.
36. 3): δ 169.2, 139.9, 137.1, 133.8, 129.2, 129.0, 128.4, 128.2, 126.1, 101.8, 76.8, 76.7, 73.9, 73.7, 73.4, 70.3, 69.0, 58.0, 34.2, 33.7, 20.9.
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40. 3): δ 170.2, 140.5, 133.4, 128.9, 128.0, 77.7, 74.5, 70.5, 58.4, 34.9, 31.6, 29.8, 29.2, 24.9, 22.6, 21.1, 14.1.
41. 3): δ 170.2, 140.5, 133.4, 128.9, 128.0, 77.7, 74.5, 70.4, 58.4, 34.9, 31.6, 29.8, 29.21, 29.16, 24.9, 22.6, 21.1, 14.1.
42. The other two products should be stereoisomers.
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