Involvement of intramolecular hydride transfer in the formation of alkanes from palladium alkyls

Organometallics

Volumn 16, Issue 19, 1997, Pages 4030-4032

  Albéniz, Ana C ^a   Espinet, Pablo ^a   Lin, Yong Shou ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001612711     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9703651     Document Type: Article

References (22)

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10. β).
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12. 79), D, 272 (15), 271 (100), 250 (19), 251 (19), 201 (12), 171 (8), 169 (9), 103 (10), 89 (10), 78 (9), 77 (12), 63 (10), 51 (17).
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15. Intramolecular refers here to a process occurring in a dimer. The presence of bridging Br assists the formation of a bridging H needed for a direct Pd to Pd hydride transfer (see main text).
16. Scott, J. D.; Puddephatt, R. J. Organometallics 1983, 2, 1643.
17. (a) Bronger, W.; à Brassard, L. Angew. Chem., Int. Ed. Engl. 1995, 34, 898.
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21. ortho).
22. 3, 273 K): 7.9-7.3 (m, 30H, aromatic), -11.82 (t, 1H, J = 9.5 Hz). These data agree with those reported previously for the hydride complex, see: Heaton, B. T.; Hébert, S. P. A.; Iggo, J. A.; Metz, F.; Whyman, R. J. Chem. Soc., Dalton Trans. 1993, 3081.