Reactivity of Pd(0)(NHC)2 (NHC: N-heterocyclic carbene) in oxidative addition with aryl halides in heck reactions

Synlett

Volumn , Issue 18, 2006, Pages 3088-3094

  Roland, Sylvain ^a   Mangeney, Pierre ^a   Jutand, Army ^b  

^a CNRS   (France)

^b ECOLE NORMALE SUPÉRIEURE   (France)

Author keywords

Heck reactions; Kinetics; Mechanism; NHC carbene; Oxidative addition; Palladium

Indexed keywords

1,3 DI BENZYL 4,5 DI TERT BUTYLIMIDAZOLIDIN 2 YLIDENE; 1,3 DI TERT BUTYLIMIDAZOLIDIN 2 YLIDENE; ALKENE DERIVATIVE; CARBENE; CARBENOID; CHLORIDE; HALIDE; HETEROCYCLIC COMPOUND; PALLADIUM COMPLEX; UNCLASSIFIED DRUG;

AEROBIC METABOLISM; ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; DISSOCIATION; HECK REACTION; ROOM TEMPERATURE;

EID: 33751277480     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-951519     Document Type: Article

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46. inv is the inversion potential of the scan).
47. 1/2 was determined as indicated in Figure 8.
48. 18b Consequently, species present at low thermodynamic concentrations in endergonic equilibrium may be detected by cyclic voltammetry performed at low scan rates.
49. -1, δt = 100 s).
50. 3.
51. 4Cl (from 0.03-0.45 M).