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3Cl tetrahedra are only known from single crystal X-ray structure determinations of chloroborosubphthalocyanine compounds. Compared with ClTp in 2, these compounds show systematically shorter B-N bonds (mean value 1.480(11)), longer B-Cl bonds (mean value 1.862(7) Å, 1.839(2) Å in 2) and N-B-N angles which are smaller by about 8° compared to the N-B-Cl angles (105° and 113°, respectively)
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3Cl tetrahedra are only known from single crystal X-ray structure determinations of chloroborosubphthalocyanine compounds. Compared with ClTp in 2, these compounds show systematically shorter B-N bonds (mean value 1.480(11)), longer B-Cl bonds (mean value 1.862(7) Å, 1.839(2) Å in 2) and N-B-N angles which are smaller by about 8° compared to the N-B-Cl angles (105° and 113°, respectively). Fukuda T., Stork J.R., Potucek R.J., Olmstead M.M., Noll B.C., Kobayashi N., and Durfee W.S. Angew. Chem., Int. Ed. 41 (2002) 2565
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45
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Bruker programs: SMART, version 5.625; SAINT, version 6.54; SADABS, version 2.10; SHELXTL, version 6.1 (Bruker AXS Inc., Madison, WI, 2003).
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