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For the activation of haloalkanes by metal complexes, see: (a) Simal, F.; Wlodarczak, L.; Demonceau, A.; Noels, A. F. Tetrahedron Lett. 2000, 41, 6071.
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14
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0030790904
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and references therein
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2 acts as a ligand in metal complexes, see: Huang, D.; Huffman, J. C.; Bollinger, J. C.; Eisentein, O.; Caulton, K. G. J. Am. Chem. Soc. 1997, 119, 7398, and references therein.
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17
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0001068271
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Gamasa, M. P.; Gimeno, J.; Gonzalez-Bernardo, C.; Martín-Vaca, B. M.; Monti, D.; Bassetti, M. Organometallics 1996, 15, 302.
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24
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0011529536
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note
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The use of potassium tert-butoxide instead of 2-propanol/KOH was not effective for the production of 2 in the reaction of 1 with dichloromethane.
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-
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25
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85086684943
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note
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3 (3 equiv) was added.
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26
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0011531359
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note
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It is also possible that complex 2 is formed via the formation of a carbene complex from the chloromethyl intermediate. See refs 4c and 8c.
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-
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27
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0011590961
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and references therein
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For examples of using chloroform and KOH for in situ generation of metal carbonyl complexes, see: Grushin, V. V.; Alper, H. Organometallics 1993, 12, 3846, and references therein.
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(1993)
Organometallics
, vol.12
, pp. 3846
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Grushin, V.V.1
Alper, H.2
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