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Volumn 20, Issue 9, 2001, Pages 1892-1894

Reactions of (η5-indenyl)Ru(PPh3)2Cl with CH2Cl2 and CHCl3: Formation of (η5-indenyl)Ru{CH2PPh2 (C6H4)} (PPh3) and (η5-indenyl)Ru(PPh3)(CO)Cl

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; COMPLEXATION; MOLECULAR STRUCTURE; ORGANOMETALLICS; POTASSIUM COMPOUNDS; REACTION KINETICS;

EID: 0035972365     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om001003n     Document Type: Article
Times cited : (19)

References (27)
  • 17
    • 0001068271 scopus 로고    scopus 로고
    • For examples of the formation of cyclic metal phosphorus ylide complexes through orthometalation, see: (a) Koch, J. L.; Shapley, P. A. Organometallics 1999, 18, 814.
    • (1999) Organometallics , vol.18 , pp. 814
    • Koch, J.L.1    Shapley, P.A.2
  • 24
    • 0011529536 scopus 로고    scopus 로고
    • note
    • The use of potassium tert-butoxide instead of 2-propanol/KOH was not effective for the production of 2 in the reaction of 1 with dichloromethane.
  • 25
    • 85086684943 scopus 로고    scopus 로고
    • note
    • 3 (3 equiv) was added.
  • 26
    • 0011531359 scopus 로고    scopus 로고
    • note
    • It is also possible that complex 2 is formed via the formation of a carbene complex from the chloromethyl intermediate. See refs 4c and 8c.
  • 27
    • 0011590961 scopus 로고
    • and references therein
    • For examples of using chloroform and KOH for in situ generation of metal carbonyl complexes, see: Grushin, V. V.; Alper, H. Organometallics 1993, 12, 3846, and references therein.
    • (1993) Organometallics , vol.12 , pp. 3846
    • Grushin, V.V.1    Alper, H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.