Double geminal C-H activation and reversible α-elimination in 2-aminopyridine iridium(III) complexes: The role of hydrides and solvent in flattening the free energy surface

Journal of the American Chemical Society

Volumn 126, Issue 28, 2004, Pages 8795-8804

  Clot, Eric ^b   Chen, Junyi ^a   Lee, Dong Heon ^c   Sung, So Young ^c   Appelhans, Leah N ^a   Faller, Jack W ^a   Crabtree, Robert H ^a   Eisenstein, Odile ^b  

^a YALE UNIVERSITY   (United States)

^b UNIV MONTPELLIER   (France)

^c Chonbuk National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; AMINES; COMPLEXATION; COMPUTATIONAL METHODS; DRUG PRODUCTS; FREE ENERGY; HYDRIDES; HYDROGEN BONDS; IRIDIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE; REACTION KINETICS; SOLVENTS;

CARBENES; ELIMINATION REACTIONS; SELECTIVE ISOTOPE EXCHANGES;

CATALYSTS;

2 (DIMETHYLAMINO)PYRIDINE; 2 AMINOPYRIDINE; ACETONE; ALKYL GROUP; CARBENE; CHELATE; PYRIDINE DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; COMPLEX FORMATION; CYCLIZATION; ELIMINATION REACTION; ENERGY; HYDROGEN BOND; ISOMER; METAL BINDING; NUCLEAR MAGNETIC RESONANCE; OXIDATION; REACTION ANALYSIS; TITRIMETRY;

EID: 3242734588     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja048473j     Document Type: Article

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