-
1
-
-
0002646131
-
-
Coughlan, M. P., Ed.; Pergamon Press: Oxford, U. K.
-
Rajagopalan, K. V. In Molybdenum and Molybdenum-Containing Enzymes; Coughlan, M. P., Ed.; Pergamon Press: Oxford, U. K., 1980; pp 243-272.
-
(1980)
Molybdenum and Molybdenum-Containing Enzymes
, pp. 243-272
-
-
Rajagopalan, K.V.1
-
3
-
-
0035861646
-
-
Eilers, T.; Schwarz, G.; Brinkmann, H.; Witt, C.; Richter, T.; Nieder, J.; Koch, B.; Hille, R.; Hänsch, R.; Mendel, R. R. J. Biol. Chem. 2001, 276, 46989-46994.
-
(2001)
J. Biol. Chem.
, vol.276
, pp. 46989-46994
-
-
Eilers, T.1
Schwarz, G.2
Brinkmann, H.3
Witt, C.4
Richter, T.5
Nieder, J.6
Koch, B.7
Hille, R.8
Hänsch, R.9
Mendel, R.R.10
-
4
-
-
0141842750
-
-
(b) Hille, R. Structure 2003, 11, 1189-1197.
-
(2003)
Structure
, vol.11
, pp. 1189-1197
-
-
Hille, R.1
-
5
-
-
0141483198
-
-
(c) Schrader, N.; Fischer, K.; Theis, K.; Mendel, R. R.; Schwartz, G.; Kisker, K. Structure 2003, 11, 1251-1263.
-
(2003)
Structure
, vol.11
, pp. 1251-1263
-
-
Schrader, N.1
Fischer, K.2
Theis, K.3
Mendel, R.R.4
Schwartz, G.5
Kisker, K.6
-
6
-
-
0034607799
-
-
Kappler, U.; Bennett, B.; Rethmeier, J.; Schwarz, G.; Deutzmann, R.; McEwan, A. G.; Dahl, C. J. Biol. Chem. 2000, 275, 13202-13212.
-
(2000)
J. Biol. Chem.
, vol.275
, pp. 13202-13212
-
-
Kappler, U.1
Bennett, B.2
Rethmeier, J.3
Schwarz, G.4
Deutzmann, R.5
McEwan, A.G.6
Dahl, C.7
-
7
-
-
30744479483
-
-
D'Errico, G.; Di Salle, A.; La Cara, F.; Rossi, M.; Cannio, R. J. Bacteriol. 2006, 188, 694-701.
-
(2006)
Bacteriol.
, vol.188
, pp. 694-701
-
-
D'Errico, G.1
Di Salle, A.2
La Cara, F.3
Rossi, M.4
Cannio, R.J.5
-
9
-
-
20744437113
-
-
Rees, D. C.; Tezcan, A.; Haynes, C. A.; Walton, M. Y.; Andrade, S.; Einsle, O.; Howard, J. B. Philos. Trans. R. Soc. A. 2005, 363, 971-984.
-
(2005)
Philos. Trans. R. Soc. A.
, vol.363
, pp. 971-984
-
-
Rees, D.C.1
Tezcan, A.2
Haynes, C.A.3
Walton, M.Y.4
Andrade, S.5
Einsle, O.6
Howard, J.B.7
-
12
-
-
0028838798
-
-
Molybdenum enzymes have previously been described as all involving two-electron redox chemistry at molybdenum, coupled with the transfer of an oxygen atom. While this is true for the majority of molybdenum enzymes (and for their close relatives the tungsten enzymes), there are some exceptions. The tungsten enzyme acetylene hydratase (Rosner, B. M.; Schink, B. J. Bacteriol. 1995, 177, 5767-5772)
-
(1995)
J. Bacteriol.
, vol.177
, pp. 5767-5772
-
-
Rosner, B.M.1
Schink, B.2
-
13
-
-
0032502268
-
-
2 by Eschencia coli formate dehydrogenase H does not involve oxygen atom transfer (Khangulov, S. V.; Gladyshev, V. N.; Dismukes, G. C.; Stadtman, T. C. Biochemistry, 1998, 37, 3518-3528).
-
(1998)
Biochemistry
, vol.37
, pp. 3518-3528
-
-
Khangulov, S.V.1
Gladyshev, V.N.2
Dismukes, G.C.3
Stadtman, T.C.4
-
14
-
-
0032542583
-
-
Furthermore, the presence of the potentially redox-active seleno-sulfide at the active site (George, G. N.; Colangelo, C. M.; Dong, J.; Scott, R. A.; Khangulov, S. V.; Gladyshev, V. N.; Stadtman, T. C. J. Am. Chem. Soc. 1998, 120, 1267-1273),
-
(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 1267-1273
-
-
George, G.N.1
Colangelo, C.M.2
Dong, J.3
Scott, R.A.4
Khangulov, S.V.5
Gladyshev, V.N.6
Stadtman, T.C.7
-
15
-
-
0033599569
-
-
suggests that the molybdenum in formate dehydrogenases might not be redox active during the catalysis (George, G. N.; Costa, C.; Moura, J. J. G.; Moura, I. J. Am. Chem. Soc. 1999, 121, 2625-2626).
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 2625-2626
-
-
George, G.N.1
Costa, C.2
Moura, J.J.G.3
Moura, I.4
-
16
-
-
0003422833
-
-
Kisker, C.; Schindelin, H.; Pacheco, A.; Wehbi, W. A.; Garrett, R. M.; Rajagopalan, K. V.; Enemark, J. E.; Rees, D. C. Cell 1997, 91, 1-20.
-
(1997)
Cell
, vol.91
, pp. 1-20
-
-
Kisker, C.1
Schindelin, H.2
Pacheco, A.3
Wehbi, W.A.4
Garrett, R.M.5
Rajagopalan, K.V.6
Enemark, J.E.7
Rees, D.C.8
-
17
-
-
25844438768
-
-
(b) Karakas, E.; Wilson, H. L.; Graf, T. N.; Xiang, S.; Jaramillo-Busquets, S.; Rajagopalan K. V.; Kisker, C. J. Biol. Chem. 2005, 280, 33506-33515.
-
(2005)
J. Biol. Chem.
, vol.280
, pp. 33506-33515
-
-
Karakas, E.1
Wilson, H.L.2
Graf, T.N.3
Xiang, S.4
Jaramillo-Busquets, S.5
Rajagopalan, K.V.6
Kisker, C.7
-
18
-
-
0000273676
-
-
Hille, R. Chem. Rev. 1996, 96, 2757-2816.
-
(1996)
Chem. Rev.
, vol.96
, pp. 2757-2816
-
-
Hille, R.1
-
19
-
-
31544439387
-
-
Harris, H. H.; George, G. N.; Rajagopalan, K. V. Inorg. Chem. 2006, 45, 493-495.
-
(2006)
Inorg. Chem.
, vol.45
, pp. 493-495
-
-
Harris, H.H.1
George, G.N.2
Rajagopalan, K.V.3
-
20
-
-
0032704113
-
-
George, G. N.; Mertens, J. A.; Campbell, W. A. J. Am. Chem. Soc. 1999, 121, 9730-9731.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 9730-9731
-
-
George, G.N.1
Mertens, J.A.2
Campbell, W.A.3
-
21
-
-
22544435739
-
-
Fischer, K.; Barbier, G.; Hecht, H.-J.; Mendel, R. R.; Campbell, W. H.; Schwarz, G. Plant Cell 2005, 17, 1167-1179.
-
(2005)
Plant Cell
, vol.17
, pp. 1167-1179
-
-
Fischer, K.1
Barbier, G.2
Hecht, H.-J.3
Mendel, R.R.4
Campbell, W.H.5
Schwarz, G.6
-
23
-
-
85088669124
-
-
George, G. N.; Pickering, I. J.; Kisker, C. Inorg. Chem. 2005, 38, 2539-2540.
-
(2005)
Inorg. Chem.
, vol.38
, pp. 2539-2540
-
-
George, G.N.1
Pickering, I.J.2
Kisker, C.3
-
25
-
-
33845283091
-
-
Tp* = hydrotris(3,5-dimethylpyrazolyl)borate; Cleland, W. E., Jr.; Barnhart, K. M.; Yamanouchi, K.; Collison, D.; Mabbs, F. E.; Ortega, R. B.; Enemark, J. H. Inorg. Chem. 1987, 26, 1017-1025.
-
(1987)
Inorg. Chem.
, vol.26
, pp. 1017-1025
-
-
Cleland Jr., W.E.1
Barnhart, K.M.2
Yamanouchi, K.3
Collison, D.4
Mabbs, F.E.5
Ortega, R.B.6
Enemark, J.H.7
-
26
-
-
0023325538
-
-
Cramer, S. P.; Tench, O.; Yocum, M.; George, G. N. Nucl. Instrum. Methods Phys. Res. 1988, A266, 586-591.
-
(1988)
Nucl. Instrum. Methods Phys. Res.
, vol.A266
, pp. 586-591
-
-
Cramer, S.P.1
Tench, O.2
Yocum, M.3
George, G.N.4
-
27
-
-
33748795697
-
-
The EXAFSPAK program suite was developed by one of the authors (G.N.G.) and is available from http://ssrl.slac.stanford.edu/exafspa-k.html.
-
-
-
-
28
-
-
0029816512
-
-
George, G. N.; Garrett, R. M.; Prince, R. C.; Rajagopalan, K. V. J. Am. Chem. Soc. 1996, 118, 8588-8592.
-
(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 8588-8592
-
-
George, G.N.1
Garrett, R.M.2
Prince, R.C.3
Rajagopalan, K.V.4
-
29
-
-
0001661950
-
-
Rehr, J. J.; Mustre de Leon, J.; Zabinsky, S. I.; Albers, R. C. J. Am. Chem. Soc. 1991, 113, 5135-5140.
-
(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 5135-5140
-
-
Rehr, J.J.1
Mustre De Leon, J.2
Zabinsky, S.I.3
Albers, R.C.4
-
30
-
-
33751124173
-
-
(b) Mustre de Leon, J.; Rehr, J. J.; Zabinsky, S. I.; Albers, R. C. Phys. Rev. 1991, B44, 4146-4156.
-
(1991)
Phys. Rev.
, vol.B44
, pp. 4146-4156
-
-
Mustre De Leon, J.1
Rehr, J.J.2
Zabinsky, S.I.3
Albers, R.C.4
-
31
-
-
0023761568
-
-
George, G. N.; Prince, R. C.; Kipke, C. A.; Sunde., R. A.; Enemark, J. E. Biochem. J. 1988, 256, 307-309.
-
(1988)
Biochem. J.
, vol.256
, pp. 307-309
-
-
George, G.N.1
Prince, R.C.2
Kipke, C.A.3
Sunde, R.A.4
Enemark, J.E.5
-
32
-
-
0039667195
-
-
Kutzler, F. W.; Natoli, C. R.; Misemer, D. K.; Donaich, S.; Hodgson, K. O. J. Chem. Phys. 1980, 73, 3274-3288.
-
(1980)
J. Chem. Phys.
, vol.73
, pp. 3274-3288
-
-
Kutzler, F.W.1
Natoli, C.R.2
Misemer, D.K.3
Donaich, S.4
Hodgson, K.O.5
-
33
-
-
33845558282
-
-
Cramer, S. P.; Wahl, R.; Rajagopolan, K. V. J. Am. Chem. Soc. 1981, 103, 7721-7727.
-
(1981)
J. Am. Chem. Soc.
, vol.103
, pp. 7721-7727
-
-
Cramer, S.P.1
Wahl, R.2
Rajagopolan, K.V.3
-
34
-
-
0033576980
-
-
George, G. N.; Hilton, J.; Temple, C.; Prince, R. C.; Rajagopolan, K. V. J. Am. Chem. Soc. 1999, 121, 1256-1266.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 1256-1266
-
-
George, G.N.1
Hilton, J.2
Temple, C.3
Prince, R.C.4
Rajagopolan, K.V.5
-
35
-
-
0000272057
-
-
Kutzler, F. W.; Scott, R. A.; Berg, J. M.; Hodgson. K. O.; Donaich, S.; Cramer, S. P.; Chang, C. H. J. Am. Chem. Soc. 1981, 103, 6083-6088.
-
(1981)
J. Am. Chem. Soc.
, vol.103
, pp. 6083-6088
-
-
Kutzler, F.W.1
Scott, R.A.2
Berg, J.M.3
Hodgson, K.O.4
Donaich, S.5
Cramer, S.P.6
Chang, C.H.7
-
36
-
-
33748771068
-
-
Raitsimring, A. M.; Kappler, U.; Feng, C.; Astashkin, A. V.; Enemark, J. H. Inorg. Chem. 2005, 44, 7203-7285.
-
(2005)
Inorg. Chem.
, vol.44
, pp. 7203-7285
-
-
Raitsimring, A.M.1
Kappler, U.2
Feng, C.3
Astashkin, A.V.4
Enemark, J.H.5
-
37
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33748784214
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note
-
The generally accepted accuracy for EXAFS bond-length determination is ±0.02 Å. The relative accuracy between two similar samples (e.g., oxidized and reduced enzyme) is likely to be rather better than this.
-
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38
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-
11144265898
-
-
George, G. N.; Garret, R. M.; Prince, R. C.; Rajagopalan, K. V. Inorg. Chem. 2004, 43, 8456-8460.
-
(2004)
Inorg. Chem.
, vol.43
, pp. 8456-8460
-
-
George, G.N.1
Garret, R.M.2
Prince, R.C.3
Rajagopalan, K.V.4
-
39
-
-
0001693415
-
-
George, G. N.; Garrett, R. M.; Graf, T.; Prince, R. C.; Rajagopalan, K. V. J. Am. Chem. Soc. 1998, 120, 4522-4523.
-
(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 4522-4523
-
-
George, G.N.1
Garrett, R.M.2
Graf, T.3
Prince, R.C.4
Rajagopalan, K.V.5
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40
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33748791602
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note
-
1H) is close to the magic angle in relation to g.
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-
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