-
2
-
-
0000273676
-
-
(b) Hille, R. Chem. Rev. 1996, 96. 2757-2816.
-
(1996)
Chem. Rev.
, vol.96
, pp. 2757-2816
-
-
Hille, R.1
-
3
-
-
4243627847
-
-
Johnson, M. K.; Rees, D. C.; Adams, M. W. W. Chem. Rev. 1996, 96, 2817-2859.
-
(1996)
Chem. Rev.
, vol.96
, pp. 2817-2859
-
-
Johnson, M.K.1
Rees, D.C.2
Adams, M.W.W.3
-
5
-
-
0032502268
-
-
Khangulov, S. V.; Gladyshev, V. N.; Dismukes, G. C.; Stadtman, T. C. Biochemistry 1998. 37, 3518-3528.
-
(1998)
Biochemistry
, vol.37
, pp. 3518-3528
-
-
Khangulov, S.V.1
Gladyshev, V.N.2
Dismukes, G.C.3
Stadtman, T.C.4
-
6
-
-
0032542583
-
-
George, G. N.; Colangelo, C. M.; Dong, J.; Scott, R. A.; Khangulov, S. V.; Gladyshev, V. N.; Stadtman,T. C. J. Am. Chem. Sac. 1998, 120, 1267-1273.
-
(1998)
J. Am. Chem. Sac.
, vol.120
, pp. 1267-1273
-
-
George, G.N.1
Colangelo, C.M.2
Dong, J.3
Scott, R.A.4
Khangulov, S.V.5
Gladyshev, V.N.6
Stadtman, T.C.7
-
7
-
-
0030900976
-
-
Costa, C.; Teixeira, M.; LeGall, J.. Moura. J. J. G.; Moura, I. J. Biol. Inorg. Chem. 1997, 2, 198-208.
-
(1997)
J. Biol. Inorg. Chem.
, vol.2
, pp. 198-208
-
-
Costa, C.1
Teixeira, M.2
LeGall, J.3
Moura, J.J.G.4
Moura, I.5
-
8
-
-
0032508380
-
-
VI trihydropterin species) have recently been detected in bacterial aldehyde dehydrogenases [Luykx, D. M. A.; Duine, J. A.; de Vries, S. Biochemistry 1998, 37, 11366-11375]. Although such species certainly indicate nonmetal-based redox chemistry, direct involvement of molybdenum ligands is not indicated.
-
(1998)
Biochemistry
, vol.37
, pp. 11366-11375
-
-
Luykx, D.M.A.1
Duine, J.A.2
De Vries, S.3
-
9
-
-
13044251016
-
-
6 in 50 mM N-2-hydroxyethylpiperazine-N′-2-ethanesulfonic acid buffer at pH 7.5 and frozen in 3 × 10 × 10 mm Lucite sample cuvettes. The enzyme was reduced with 10 mM sodium dithionite solution in the presence of 40 μM methyl viologen for 4 min. Dithionite was chosen in preference to formate as reductant because the latter gives rise to a mixture of oxidation states (analysis of EXAFS of mixtures can be problematic). Data were collected at a sample temperature of 10 K and 16 35-min sweeps were averaged for each sample.
-
-
-
-
10
-
-
0029816512
-
-
George, G. N.; Garrett, R. M.; Prince, R. C.; Rajagopalan, K. V. J. Am. Chem. Soc. 1996, 118, 8588-8592.
-
(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 8588-8592
-
-
George, G.N.1
Garrett, R.M.2
Prince, R.C.3
Rajagopalan, K.V.4
-
11
-
-
0001661950
-
-
(a) Rehr, J. J., Mustre de Leon, J.; Zabinsky, S. I.; Albers, R. C. J. Am. Chem. Soc. 1991, 113, 5135-5140.
-
(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 5135-5140
-
-
Rehr, J.J.1
Mustre De Leon, J.2
Zabinsky, S.I.3
Albers, R.C.4
-
12
-
-
33751124173
-
-
(b) Mustre de Leon, J.; Rehr, J. J.; Zabinsky, S. I.; Albers, R. C. Phys. Rev. 1991, B44, 4146-4156.
-
(1991)
Phys. Rev.
, vol.B44
, pp. 4146-4156
-
-
Mustre De Leon, J.1
Rehr, J.J.2
Zabinsky, S.I.3
Albers, R.C.4
-
13
-
-
13044283975
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-
note
-
2 are the Debye-Waller factors, and the values in parentheses are the estimated standard deviations (precisions) obtained from the diagonal elements of the covariance matrix.
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-
-
14
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13044270175
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note
-
We note that EXAFS cannot readily distinguish between backscatterers of similar atomic number. For example, although Se-C and Se-S EXAFS are trivial to tell apart, Se-S and Se-Cl EXAFS are not. It is therefore possible that the selenosulfide sulfur observed in the Se EXAFS is in fact a chloride. We consider this possibility unlikely, as the samples were prepared in chloride-free buffer.
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-
-
-
15
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0031043109
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-
Boyington, J. C.; Gladyshev, V. N.; Khangulov, S. V.; Stadtman, T. C.; Sun, P. D. Science 1997, 275, 1305-1308.
-
(1997)
Science
, vol.275
, pp. 1305-1308
-
-
Boyington, J.C.1
Gladyshev, V.N.2
Khangulov, S.V.3
Stadtman, T.C.4
Sun, P.D.5
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16
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13044309961
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note
-
We note that in this case the selenosulfide was retained in the dithionite-treated enzyme, although conditions of reduction differed in that no methyl viologen was added.
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18
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0027933267
-
-
Gladyshev, V. N.; Khangulov, S. V.; Axley, M. J.; Stadtman, T. C. Proc. Natl. Acad. Sci. U.S.A. 1994, 91, 7708-7711.
-
(1994)
Proc. Natl. Acad. Sci. U.S.A.
, vol.91
, pp. 7708-7711
-
-
Gladyshev, V.N.1
Khangulov, S.V.2
Axley, M.J.3
Stadtman, T.C.4
-
20
-
-
0000083402
-
-
III EPR studies of well-characterized complexes with ligands that are not biologically relevant [e.g., Pleune, B.; Poli, R.; Fettinger, J. C. J. Am. Chem. Soc. 1998, 120, 3257-3258].
-
(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 3257-3258
-
-
Pleune, B.1
Poli, R.2
Fettinger, J.C.3
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