Formation of acetic acid by aqueous-phase oxidation of ethanol with air in the presence of a heterogeneous gold catalyst

Angewandte Chemie - International Edition

Volumn 45, Issue 28, 2006, Pages 4648-4651

  Christensen, Claus H ^a   Jørgensen, Betina ^a   Rass Hansen, Jeppe ^a   Egeblad, Kresten ^a   Madsen, Robert ^a   Klitgaard, Søren K ^a   Hansen, Stine M ^a   Hansen, Mike R ^a   Andersen, Hans C ^a   Riisager, Anders ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Acetic acid; Bioethanol; Gold; Heterogeneous catalysis; Oxidation

Indexed keywords

ACIDIC MEDIA; BIOETHANOL; OXIDANT; VINEGAR;

BYPRODUCTS; CATALYSIS; ETALONS; GOLD; OXIDATION; TRANSMISSION ELECTRON MICROSCOPY;

ACETIC ACID;

ACETIC ACID; ALCOHOL; GOLD;

AIR; ARTICLE; CATALYSIS; CHEMISTRY; OXIDATION REDUCTION REACTION; SYNTHESIS;

ACETIC ACID; AIR; CATALYSIS; ETHANOL; GOLD; OXIDATION-REDUCTION;

EID: 33746291313     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200601180     Document Type: Article

References (32)

1. J. W. Döbereiner, Ann. Phys. 1822, 72, 193.
2. H. Cheung, R. S. Tanke, G. P. Torrence, Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.
3. S. Kim, B. E. Dale, Biomass Bioenergy 2004, 26, 361.
4. R. Wooley, M. Ruth, D. Glassner, J. Sheehan, Biotechnol. Prog. 1999, 15, 794.
5. Y. Obana, H. Uchida, K.-i. Sano, US Patent 6,867,164, 2005.
6. J. Schwank, Gold Bull. 1983, 16, 103.
7. M. Haruta, T. Kobayashi, H. Sano, N. Yamada, Chem. Lett. 1987, 405.
8. M. Haruta, N. Yamada, T. Kobayashi, S. Iilima, J. Catal. 1989, 115, 301.
9. G. J. Hutchings, J. Catal. 1985, 96, 292.
10. T. Mallat, A. Baiker, Catal. Today 1994, 19, 247.
11. G. J. Hutchings, M. Haruta, Appl. Catal. A 2005, 291, 2.
12. G. J. Hutchings, Catal. Today 2005, 100, 55.
13. G-J. ten Brink, I. W. C. E. Arends, R. A. Sheldon, Science 2000, 287, 1636.
14. K. Mori, T. Hara, T. Mizugaki, K. Ebitani, K. Kaneda, J. Am. Chem. Soc. 2004, 126, 10 657.
15. T. Nishimura, N. Kakiuchi, M. Inoue, S. Uemura, Chem. Commun. 2000, 1245.
16. L. Prati, M. Rossi, J. Catal. 1998, 176, 552.
17. C. Bianchi, F. Porta, L. Prati, M. Rossi, Top. Catal. 2000, 13, 231.
18. S. Carretin, P. McMorn, P. Johnston, K. Griffin, C. J. Kiely, G. J. Hutchings, Chem. Commun. 2002, 696.
19. A. Abad, P. Concepción, A. Corma, H. Garcia, Angew. Chem. 2005, 117, 4134;
20. Angew. Chem. Int. Ed. 2005, 44, 4066.
21. D. I. Enache, D. W. Knight, G. J. Hutchings, Catal. Lett. 2005, 103, 43.
22. G. Soboèan, P. Glaviè, Appl. Therm. Eng. 2000, 20, 529.
23. M. S. Chen, D. W. Goodman, Science 2004, 306, 252.
24. G. Fornasari, R. Glöckler, M. Livi, A. Vaccari, Appl. Clay Sci. 2005, 20, 258.
25. A. Haryanto, S. Fernando, N. Murali, S. Adhikari, Energy Fuels 2005, 19, 2098.
26. G. A. Deluga, J. R. Salge, L. Schmidt, X. E. Verykios, Science 2004, 303, 993.
27. Bioethanol, acetaldehyde, ethene, butadiene, acetic acid, and gasoline are currently produced in quantities of about 30, 1.4, 120, 7.5, 8.5, and 1100 million tonnes per year, respectively.
28. R. D. Cortright, R. R. Davda, J. A. Dumesic, Nature 2002, 418, 964.
29. J. R. Rostrup-Nielsen, Science 2005, 308, 1421.
30. G. W. Huber, J. N. Cheeda, C. J. Barrett, J. A. Dumesic, Science 2005, 308, 1446.
31. M. Haruta, Catal. Today 1997, 36, 153.
32. J. Dohrup, C. J. H. Jacobsen, C. Olsen, US Patent 6,416,731, 2002.