Formation of zirconocene fluoro complexes: No deactivation in the polymerization of olefins by the contact-ion-pair catalysts [Cp′ 2ZrR]+[RB(C6F5)3] -

Angewandte Chemie - International Edition

Volumn 45, Issue 25, 2006, Pages 4195-4198

  Arndt, Perdita ^a   Jäger Fiedler, Ulrike ^a   Klahn, Marcus ^a   Baumann, Wolfgang ^a   Spannenberg, Anke ^a   Burlakov, Vladimir V ^b   Rosenthal, Uwe ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

Borate ligands; C F activation; Homogeneous catalysis; Polymerization; Zirconocene fluorides

Indexed keywords

CATALYST ACTIVITY; CHEMICAL BONDS; COMPLEXATION; OLEFINS; POLYMERIZATION;

BORATE LIGANDS; C-F ACTIVATION; HOMOGENEOUS CATALYSIS; ZIRCONOCENE FLUORIDES;

AROMATIC COMPOUNDS;

EID: 33746285844     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600361     Document Type: Article

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39. -3, 17564 reflections measured, 5159 independent, 3562 observed (I > 2σ(I)), R1 = 0.057, wR2(all data) = 0.141, 696 parameters. The terminal hydride ligand was not located.
40. -3, 17145 reflections measured, 5104 independent, 3749 observed (I > 2σ(I)), R1 = 0.034, wR2(all data) = 0.061, 487 parameters.
41. -3, 16976 reflections measured, 5992 independent, 2908 observed (I > 2σ(I)), R1 = 0.053, wR2(all data) = 0.153, 507 parameters. CCDC-295535 (3), CCDC-295534 (4), and CCDC-295536 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.