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3 adducts due to rearrangement has been observed in a few specific cases; however, these usually involve formal transfer and insertion of the alkylidene unit into the B-C bond. See, e.g.: Köster, R.; Rickborn, B. J. Am. Chem. Soc. 1967, 89, 2782. For additional examples of reactions between phosphorus ylides and borane reagents, see, e.g.: Bestmann, H. J.; Sühs, K.; Röder, T. Angew. Chem. 1981, 93, 1098; Angew. Chem., Int. Ed. Engl. 1981, 20, 1038. Bestmann H. J.; Arenz, T. Angew. Chem. 1984, 96, 363; Angew. Chem., Int. Ed. Engl. 1984, 23, 381; Angew. Chem. 1986, 98, 571; Angew. Chem., Int. Ed. Engl. 1986, 25, 559. See also: Köster, R. In Houben-Weyl. Methoden der Organischen Chemie; Thieme: Stuttgart, 1983; Vol. 13/3b, p 706-7 and references therein.
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