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For example, alkanethiols can adsorb either laterally or perpendicularly to gold depending on the adsorption mechanism. Different chain lengths result in the same structure perpendicularly but have different periodicities when lying lengthwise. See: Darling, S. B.; Rosenbaum, A. W.; Wang, Y.; Sibener, S. J. Langmuir 2002, 18, 7462-7468.
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The n-carboxylic acids are pseudopolymorphic at the liquid/graphite interface. One motif consists of interdigitated dimers, in which the periodicity is only one molecular length. In the other motif dimers are not interdigitated and the periodicity is doubled. See: Hoeppener, S.; Chi, L.; Fuchs, H. ChemPhysChem 2003, 4, 494-498.
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The Epicalc program finds that the monolayer is coincident with a supercell of 12.4 nm × 8.0 nm, coming into registry with the HOPG underlayer every four unit cells along the b axis. This matches the repeating pattern observed in Figure 2c. See: Hillier, A. C.; Ward, M. D. Phys. Rev. B 1996, 54, 14037-14051.
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note
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This decrease in resolution cannot be attributed to a moiré pattern because it is consistent within a column of alkyl chains while a moiré pattern varies along this direction, as in Figure 2c.
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33745748442
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note
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The structural assignment of the cocrystal of 18-meta/18-ortho is based on the assumption that all 18-meta columns have the same orientation. An assignment of p2, containing four 18-meta and four 18-ortho molecules in the unit cell, with a doubled a-axis, would result from the alternating orientation of the 18-meta columns. The specific arrangement adopted cannot be unambiguously determined from the STM images.
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