Dynamics in physisorbed monolayers of 5-alkoxy-isophthalic acid derivatives at the liquid/solid interface investigated by scanning tunneling microscopy

Chemistry - A European Journal

Volumn 6, Issue 20, 2000, Pages 3739-3746

  Gesquière, André ^a   Abdel Mottaleb, Mohamed M ^a   De Feyter, Steven ^a   De Schryver, Frans C ^a   Sieffert, Michel ^b   Müllen, Klaus ^b   Calderone, Anna ^c   Lazzaroni, Roberto ^c   Brédas, Jean Luc ^c  

^a UNIVERSITY OF LEUVEN   (Belgium)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

^c UNIVERSITY OF MONS   (Belgium)

Author keywords

Liquid solid interface; Monolayers; Scanning probe microscopy; Self assembly

Indexed keywords

5 ALKOXYISOPHTHALIC ACID DERIVATIVE; FLUORINE DERIVATIVE; FUNCTIONAL GROUP; ISOPHTHALIC ACID; OCTANOL; SOLVENT; UNCLASSIFIED DRUG; UNDECANOL;

ADSORPTION; ARTICLE; IMAGE ANALYSIS; LIQUID; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR STABILITY; SCANNING TUNNELING MICROSCOPY; SOLID; SUPERNATANT; SURFACE PROPERTY;

EID: 0042449117     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20001016)6:20<3739::AID-CHEM3739>3.0.CO;2-1     Document Type: Article

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37. This difference in stabilization energy also accounts for the low ratio of semi-fluorinated molecules with respect to non-fluorinated molecules in the observed mixed monolayers, even though the solution from which the monolayer is formed has a 1:1 molar ratio. Similarly, it accounts for the preferential readsorption of non-fluorinated molecules.