Terminal titanium(IV) (trimethylsilyl)imides prepared by oxidatively induced trimethylsilyl abstraction

Organometallics

Volumn 25, Issue 11, 2006, Pages 2725-2728

  Bailey, Brad C ^a   Basuli, Falguni ^a   Huffman, John C ^a   Mindiola, Daniel J ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ONE-ELECTRON OXIDATION; TERMINAL TITANIUM(IV) (TRIMETHYLSILYL)IMIDES; TRIMETHYLSILYL ABSTRACTION;

ELECTRONS; ORGANOMETALLICS; OXIDATION; SYNTHESIS (CHEMICAL);

TITANIUM COMPOUNDS;

EID: 33745753887     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060168e     Document Type: Article

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30. 3SiOTf are formed in approximately a 3:1 ratio.
31. 3SiCl (∼3 equiv) to 3 led only to 25% conversion to 5 after ∼3 h.