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33745116769
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note
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The molecular weight of the samples was determined by SEC of the corresponding parent uncharged precursors in THF for P2VP and in THF/triethylamine (95:5) for PMADAME, using polystyrene standards.
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Detailed synthesis and characterization of the PMADAME-Py will be published elsewhere
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Detailed synthesis and characterization of the PMADAME-Py will be published elsewhere.
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Recently Kasumov et al. demonstrated that the observed variations of the molecular thickness of ds-DNA determined by TM-AFM are due to differences in the "molecule-substrate" interactions, which result in different compressing deformations of the molecule rather than because of the tip-induced deformations. Thus, TM-AFM reflects "real' conformations of the ds-DNA if the highest possible value of the amplitude set point is applied: A.Y. Kasumov, D. V. Klinov, P.-E. Roche, S. Gueron, H. Bouchiat, Appl. Phys. Lett. 2004, 84, 1007.
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An increase in the molecular thickness for chains swollen by vapors of a "good" solvent has also been reported: W. Zhuang, C. Ecker, G. A. Metselaar, A. E. Rowan, R. J. M. Nolle, P. Samorí, J. P. Rabe, Macromolecules 2005, 38, 473.
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Here "local" conformations are conformations of macromolecular repeat units
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Here "local" conformations are conformations of macromolecular repeat units.
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33
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33745163766
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note
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The term "helical conformation" does not reflect perfect helical order, such as in peptides or in ds-DNA, but only emphasizes that a considerable fraction of the macromolecular repeat units are organized in such a way that emanating adjacent side groups form a dihedral angle of about 90.
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0031238845
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