The first stable β-fluorosilylanion

Journal of the American Chemical Society

Volumn 125, Issue 12, 2003, Pages 3414-3415

  Fischer, Roland ^a   Baumgartner, Judith ^a   Kickelbick, Guido ^a   Marschner, Christoph ^a  

^a GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

[No Author keywords available]

Indexed keywords

ANION; ANTHRACENE; BROMIDE; CROWN ETHER; FLUORIDE; FLUORINE; HALIDE; LITHIUM DERIVATIVE; MAGNESIUM DERIVATIVE; ORGANIC COMPOUND; OXIDE; POTASSIUM; POTASSIUM DERIVATIVE; SILANE DERIVATIVE; SILICON DERIVATIVE; SOLVENT; TRIS(TRIMETHYLSILYL)SILYL HALIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; PROTON TRANSPORT; REACTION ANALYSIS; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS; TECHNIQUE; X RAY DIFFRACTION;

EID: 0037467446     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0291639     Document Type: Article

References (25)

1. Present address: Institut für Materialchemie, Technische Universität Wien, Getreidemarkt 9/165, 1060 Wien, Austria.
2. Boudier, A.; Bromm, L. O.; Lotz, M.; Knochel, P. Angew. Chem. 2000, 112, 4585; Angew. Chem., Int. Ed. 2000, 39, 4415.
3. Boudier, A.; Bromm, L. O.; Lotz, M.; Knochel, P. Angew. Chem. 2000, 112, 4585; Angew. Chem., Int. Ed. 2000, 39, 4415.
4. (a) Tamao, K.; Kawachi, A. Angew. Chem. 1995, 107, 886; Angew. Chem., Int. Ed. 1995, 34 818.
5. (a) Tamao, K.; Kawachi, A. Angew. Chem. 1995, 107, 886; Angew. Chem., Int. Ed. 1995, 34 818.
6. (b) Kawachi, A.; Tamao, K. Organometallics 1996, 15, 4653.
7. Wiberg, N.; Niedermayer, W. J. Organomet. Chem. 2001, 628, 57.
8. Jones, R. G.; Holder, S. J. In Silicon-Containing Polymers: Jones, R. G., Ando, W., Chojnowski, J., Eds.; Kluwer Publishers: Norwell, MA, 2000; pp 353-373.
9. (a) Wiberg, N.; Niedermayer, W.; Polbom, K. Z. Anorg. Allg. Chem. 2002. 628, 1045.
10. (b) Wiberg, N.; Auer, H.; Wagner, S.; Polbom, K.; Kramer, G. J. Organomet. Chem. 2001, 619, 110.
11. (a) Marschner, Ch. Eur. J. Inorg. Chem. 1998, 221.
12. (b) Kayser, Ch.; Fischer, R.; Baumgartner, J.; Marschner, Ch. Organometallics 2002, 21, 1023.
13. (c) Kayser, Ch.; Kickelbick, G.; Marschner, Ch. Angew. Chem. 2002, 114, 1031; Angew. Chem., Int. Ed. 2002, 41, 989.
14. (c) Kayser, Ch.; Kickelbick, G.; Marschner, Ch. Angew. Chem. 2002, 114, 1031; Angew. Chem., Int. Ed. 2002, 41, 989.
15. Bürger, H.; Kilian, W.; Burczyk, K. J. Organomet. Chem. 1970, 21, 291.
16. 6) -213.5.
17. Bent, H. Chem. Rev. 1961, 61, 275.
18. 3, R1 = 0.0588, wR2 = 0.1440, GOF = 1.028 (CCDC 196311).
19. 29Si CP-MAS NMR spectra of crystalline 2 carried out after submission of this manuscript confirmed the disorder observed in the crystal structure.
20. Apeloig, Y.; Yuzefovich, M.; Bendikov, M.; Bravo-Zhivotovskii, D.; Klinkhammer, K. Organometallics 1997, 16, 1265.
21. (a) Shen, Y.-S.; Gaspar, P. Organometallics 1982, 1, 1410.
22. (b) Matsumoto, H.; Yokoyama, N.; Sakamoto, A.; Aramaki, Y.; Endo, R.; Nagai, Y. Chem. Lett. 1986, 1643.
23. 2Si).
24. 3SiOMe in the presence of anthracene: Nakadaira, Y.; Kobayashi, T.; Otsuka, T.; Sakurai, H. J. Am. Chem. Soc. 1979, 101, 486.
25. 3, R1 = 0.0532, wR2 = 0.1212, GOF = 1.037 (CCDC 201304).