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Volumn 3, Issue 9, 1997, Pages 1418-1431

Tris(trimethylsilyl)silanides of the heavier alkali metals-A structural study

Author keywords

Ab initio calculations; Alkali metals; Si ligands; Silicon; Structure elucidation

Indexed keywords


EID: 0030853664     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.19970030908     Document Type: Article
Times cited : (165)

References (66)
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    • Similar interactions are also present in all alkali metal methanides. But note that here the methyl groups bear a full negative charge [review in E. Weiss, Angew. Chem. 1993, 105, 1565; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501].
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    • 3 was investigated earlier [P. Mallela, R. Geanangel, Inorg. Chem. 1993, 32, 5623]. The authors did not recognize that the crystals were twinned and therefore their values for bond lengths and angles were falsified.
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    • 3 was investigated earlier [P. Mallela, R. Geanangel, Inorg. Chem. 1993, 32, 5623]. The authors did not recognize that the crystals were twinned and therefore their values for bond lengths and angles were falsified.
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