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Hypersilane and supersilane were proposed as trivial names for tris(trimethylsilyl)silane and tri-tert-butylsilane, respectively
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Poland
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Hypersilane and supersilane were proposed as trivial names for tris(trimethylsilyl)silane and tri-tert-butylsilane, respectively, by N. Wiberg during the Xth International Symposium on Organosilicon Chemistry in Poznan (Poland).
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Examples in: a) E. N. Gladyshev, E. A. Feodorova, L. O. Yuntila, G. A. Razuvaev, N. S. Vyazankin, J. Organomet. Chem. 1975, 96, 169; b) A. M. Arif, A. H. Cowley, T. M. Elkins, R. A. Jones, J. Chem. Soc. Chem. Commun. 1986, 1777; A. M. Arif, A. H. Cowley, T. M. Elkins, J. Organomet. Chem. 1987, 325, C11.
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Examples in: a) E. N. Gladyshev, E. A. Feodorova, L. O. Yuntila, G. A. Razuvaev, N. S. Vyazankin, J. Organomet. Chem. 1975, 96, 169; b) A. M. Arif, A. H. Cowley, T. M. Elkins, R. A. Jones, J. Chem. Soc. Chem. Commun. 1986, 1777; A. M. Arif, A. H. Cowley, T. M. Elkins, J. Organomet. Chem. 1987, 325, C11.
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R. E. Benkeser, R. J. Severson, J. Am. Chem. Soc. 1951, 73, 1424; H. Gilman, T. C. Wu, ibid, 73, 4031; H. Gilman, T. C. Wu, J. Org. Chem. 1953, 18, 753; E. Wiberg, O. Stecher, H. J. Andrascheck, L. Kreuzbichler, E. Staude, Angew. Chem. 1963, 75, 516; Angew. Chem. Int. Ed. Engl. 1963, 2, 507; H. Sakurai, A. Okada, M. Kira, K. Yonezawa, Tetrahedron Lett. 1971, 1511; H. Sakurai, M. Kira, H. Umino, Chem. Lett. 1977, 1265.
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85036493935
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Private communication by N. Wiberg
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I = Na, K - are the subject of the following paper in print: N. Wiberg, K. Amelunxen, H.-W. Lerner, H. Schuster, H. Nöth, I. Krossing, M. Schmidt-Amelunxen, T. Seifert, J. Organomet. Chem. (Private communication by N. Wiberg).
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Similar interactions are also present in all alkali metal methanides. But note that here the methyl groups bear a full negative charge [review in E. Weiss, Angew. Chem. 1993, 105, 1565; Angew. Chem. Int. Ed. Engl. 1993, 32, 1501].
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