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26
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33645600792
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and references therein
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It has been reported that almost all of the silyllithium compounds exist as monomers in THF solutions, see: Tamao, K.; Kawachi, A. Adv. Organomet. Chem. 1995, 38, 1, and references therein.
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27
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0003909854
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John Wiley & Sons: Chichester, Chapter 9
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c = the coalesce temperature (K) and Δv = the chemical shift difference (Hz). Günther, H. In NMR Spectroscopy, 2nd ed.; John Wiley & Sons: Chichester, 1995; Chapter 9.
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NMR Spectroscopy, 2nd Ed.
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Günther, H.1
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0035956474
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and references therein
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In contrast, aggregation states are considered to play an important role in the inversion process of organolithium compounds, see: Hæffner, F.; Brinck, T. Organometallics 2001, 20, 5134, and references therein.
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Hæffner, F.1
Brinck, T.2
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29
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0038260542
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note
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8 and at 388 K in diglyme, according to the Lambert's procedure; see ref 5.
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