A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-

Dalton Transactions

Volumn , Issue 14, 2004, Pages 2051-2052

  García, Felipe ^a   Hopkins, Alexander D ^a   Kowenicki, Richard A ^a   McPartlin, Mary ^b   Tesa, Yolanda ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b LONDON METROPOLITAN UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; BISMUTH COMPOUNDS; CHEMICAL BONDS; NUCLEAR MAGNETIC RESONANCE; ORGANIC SOLVENTS; PHOSPHORUS; THIN FILMS;

HYPERSILYL LIGAND; LIQUID AMMONIA; METAL-METAL BOND; NUCLEOPHILE;

ANTIMONY;

EID: 3342933391     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b405032k     Document Type: Article

References (20)

1. M. A. Beswick, N. Choi, C. N. Harmer, A. D. Hopkins, M. McPartlin and D. S. Wright, Science, 1998, 281, 1500.
2. A. D. Hopkins, N. Stoodley and D. S. Wright, Patent Application No.: PCT/GB99/01078, 1998.
3. 3SiK·18-crown- 6] see Marschener et al., Eur. J. Inorg. Chem. 1998, 2, 221. The synthesis is modified in that after one hour reflux the reaction mixture is cooled to room temperature and the 18-crown-6 is added. The reaction is then refluxed for a further hour. Crude product may be obtained by precipitation with hexane.
4. S. Henkel, K. W. Klinkhammer and W. Schwarz, Angew. Chem., 1994, 106, 721; S. Henkel, K. W. Klinkhammer and W. Schwarz, Angew. Chem., Int. Ed. Engl., 1994, 33, 681.
5. S. Henkel, K. W. Klinkhammer and W. Schwarz, Angew. Chem., 1994, 106, 721; S. Henkel, K. W. Klinkhammer and W. Schwarz, Angew. Chem., Int. Ed. Engl., 1994, 33, 681.
6. K. W. Klinkhammer and W. Schwarz, Angew. Chem., 1995, 107, 1448; K. W. Klinkhammer and W. Schwarz, Angew. Chem., Int. Ed. Engl., 1995, 34, 1334.
7. K. W. Klinkhammer and W. Schwarz, Angew. Chem., 1995, 107, 1448; K. W. Klinkhammer and W. Schwarz, Angew. Chem., Int. Ed. Engl., 1995, 34, 1334.
8. G. Linti and W. Köstler, Z. Anorg. Allg. Chem., 2002, 628, 63.
9. V. O. Mundt, G. Becker and H.-J. Wessely, Z. Anorg. Allg. Chem., 1982, 486, 70.
10. M. Ates, H. J. Breunig, K. Ebert, S. Gülec, R. Kaller and M. Dräger, Organometallics, 1992, 11, 145.
11. O. M. Kekia, R. L. Jones and A. L. Rheingold, Organometallics, 1996, 15, 4104.
12. T. F. Berlitz, H. Sinning, J. Lorberth and U. Müller, Z. Naturforsch., Teil B, 1988, 43, 744.
13. M. Ates, H. J. Breunig, S. Gülec, W. Offerman, K. Häberle and M. Dräger, Chem. Ber., 1989, 122, 473.
14. Ring plane puckering angle defined as the angle between the normals of the two planes concerned.
15. Conquest software for searching the Cambridge Structural Data Base and Visualizing Crystal Structures (January, 2004), I. J. Bruno, J. C. Cole, P. R. Edgington, M. Kessler, C. F. Macrae, P. McCabe, J. Pearson and R. Taylor, Acta Crystallogr., Sect. B, 2001, 58, 389;
16. There are relatively few examples of Sb-Si bonds, the 48 reported examples lie in the range 2.442-2.671 Å. For exanples see (a) G. Becker, H. Freudenblum and C. Witthauer, Z. Anorg. Allg. Chem., 1982, 492, 37;
17. (b) M. Westerhausen, S. Weinrich and P. Mayer, Z. Anorg. Allg. Chem., 2003, 629, 1153.
18. S. C. Critchlow and J. D. Corbett, Inorg. Chem., 1984, 23, 770.
19. G. M. Sheldrick, SHELXS-P7, Program for solution of crystal structures, University of Göttingen, Germany, 1997; G. M. Sheldrick, SHELXL-97, Program for refinement of Crystal structures, University of Göttingen, Germany, 1997.
20. G. M. Sheldrick, SHELXS-P7, Program for solution of crystal structures, University of Göttingen, Germany, 1997; G. M. Sheldrick, SHELXL-97, Program for refinement of Crystal structures, University of Göttingen, Germany, 1997.