A facile and stereoselective synthesis of unsymmetrical diallylsulfides via indium-promoted one-pot reaction of Baylis-Hillman acetates, sodium thiosulfate, and allyl bromide

Synlett

Volumn , Issue 4, 2006, Pages 571-574

  Liu, Yunkui ^a   Xu, Xiangsheng ^a   Zheng, Hui ^a   Xu, Danqian ^b   Xu, Zhenyuan ^a   Zhang, Yongmin ^b,c  

^a ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

^b ZHEJIANG UNIVERSITY   (China)

^c SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

Allyl bromide; Baylis Hillman acetates; Diallylsulfides; Indium; Stereoselective

Indexed keywords

ACETIC ACID DERIVATIVE; ALLYL BROMIDE; ALLYL COMPOUND; ALLYL SULFIDE; INDIUM; SODIUM THIOSULFATE; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; BAYLIS HILLMAN REACTION; CHEMICAL STRUCTURE; PURIFICATION; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 33644996502     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-932496     Document Type: Article

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58. 4. After evaporation of solvent, the residue was purified by chromatography using cyclohexane-EtOAc (6:1) as eluent.
59. 3S: C, 64.72; H, 6.52. Found: C, 64.96; H, 6.62.