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Volumn 71, Issue 4, 2006, Pages 1545-1551

Tether-directed selective synthesis of fulleropyrrolidine bisadducts

Author keywords

[No Author keywords available]

Indexed keywords

BIS-AZOMETHINE YLIDES; C60 BISADDUCTS; STEREOISOMERS;

EID: 33644499777     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo052213i     Document Type: Article
Times cited : (27)

References (42)
  • 6
    • 0001115071 scopus 로고    scopus 로고
    • A special issue on "Functionalized fullerene materials"
    • Prato, M.; Martin, N. Eds.
    • A special issue on "Functionalized Fullerene Materials" in: Prato, M.; Martin, N. Eds. J. Mater. Chem. 2002, 7, 1931-2159.
    • (2002) J. Mater. Chem. , vol.7 , pp. 1931-2159
  • 9
    • 33644528069 scopus 로고    scopus 로고
    • la
    • (c) la.
  • 22
    • 33644500926 scopus 로고    scopus 로고
    • note
    • 2O-phenyl-) could be bound to either of the two α-carbon atoms of each pyrrolidine ring, which gives four combinations, and (2) the tertiary carbons to which the tether is attached are chiral. Thus, there could be as many as 16 theoretically possible tether linkages between the two pyrrolidine rings, depending on the symmetry of the bisaddition pattern. Numerous attempts to obtain crystals of bisadducts isomers suitable for X-ray crystallographic analysis failed.
  • 30
    • 33644522913 scopus 로고    scopus 로고
    • Reference 12b
    • (f) Reference 12b.
  • 31
    • 33644534668 scopus 로고    scopus 로고
    • note
    • See Supporting Information for the AMI energy calculation of all bisadduct isomers with use of the Spartan 04 by Wavefunction. Given the endothermicity of the present reaction, this thermodynamic argument can be readily transformed into a kinetic one by virtue of the Hammond postulate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.