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We use Hirsch's edge labeling throughout this paper because of the popularity although we developed our own edge labeling. Our labeling can express isomers more precisely than theirs, so that occasionally we apply ours for the stereochemical descriptions of compounds in footnotes; see: Nakamura, Y.; Taki, M.; Nishimura, J. Chem. Lett. 1995, 703.
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1842350475
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(A,2V)-Trisadduct (see ref 3)
-
(A,2V)-Trisadduct (see ref 3).
-
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-
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18
-
-
1842345638
-
-
note
-
It is hard to believe that cis-1-bisaddition takes place, because of the severe steric interaction between two benzocyclohexene moieties. Therefore, the addition was not taken into consideration.
-
-
-
-
19
-
-
1842322649
-
-
note
-
In this reaction, the bromination is considered to take place not only at the benzyl positions but also on the tethers and benzene rings, due to the presence of an electron-donating alkoxy group.
-
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20
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37049083678
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1842392174
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note
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2) (see ref 3).
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23
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1842347605
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note
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s for 5a,b and 6a,b due to the overlapping of some signals.
-
-
-
-
24
-
-
1842351482
-
-
Their mirror-imaged CD spectra have finally proved the enantiomeric relationship. These spectra will be reported elsewhere
-
Their mirror-imaged CD spectra have finally proved the enantiomeric relationship. These spectra will be reported elsewhere.
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26
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1842356483
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note
-
The syn and anti conformations of bisadducts are defined as follows: when one cyclohexene ring attached at a [6,6] junction is directed toward another addition site, the stereochemical situation is defined as syn, and when it faces against another, this is defined as anti.
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28
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