Rhodium and iridium complexes bearing an alkyloxazoline-substituted indenyl ligand (Indox ligand) and their stereoselective construction of metal-centered chirality

Inorganica Chimica Acta

Volumn 357, Issue 10, 2004, Pages 2965-2979

  Kataoka, Yasutaka ^a   Shimada, Koichi ^a   Goi, Takahiro ^a   Yamagata, Tsuneaki ^a   Mashima, Kazushi ^a   Tani, Kazuhide ^b  

^a OSAKA UNIVERSITY   (Japan)

^b Higashiosaka   (Japan)

Author keywords

Hemilabile; Indox ligand; Ligand exchange reaction; Metal centered chirality; Oxazoline ring; Planar chirality

Indexed keywords

CHIRALITY; ETHYLENE; ISOMERS; LIGANDS; METALS; MIXTURES; ORGANIC POLYMERS; PHOSPHORUS COMPOUNDS; RHODIUM COMPOUNDS; SPECTROSCOPIC ANALYSIS; STEREOSELECTIVITY;

HEMILABILE; LIGAND EXCHANGE REACTIONS; MONOCATIONIC COMPLEXES; OXAZOLINE RING; PLANAR CHIRALITY; RHODIUM AND IRIDIUM COMPLEXES; SPECTROSCOPIC METHOD; STEREOSELECTIVE CONSTRUCTION;

IRIDIUM COMPOUNDS;

2 [(2' (1 INDENYL)ETHYL] 4 ISOPROPYLOXAZOLINE; 2 [(3' (1 INDENYL)PROPYL] 4 ISOPROPYLOXAZOLINE; 2 [(3' (1 INDENYL)PROPYL]OXAZOLINE; ETHER; ETHYLENE; IODINE; IRIDIUM COMPLEX; LIGAND; METAL; OXAZOLINE DERIVATIVE; PHOSPHINE DERIVATIVE; POTASSIUM; PROPYLENE; RHODIUM COMPLEX; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHIRALITY; DIASTEREOISOMER; ISOMER; OXIDATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; X RAY ANALYSIS;

EID: 3242675994     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2004.05.031     Document Type: Article

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