Formation of planar-chiral alkylphosphine- and aniline-substituted cyclopentadienyl metal complexes and their reactivity toward electrophiles

Inorganica Chimica Acta

Volumn 334, Issue , 2002, Pages 253-275

  Paisner, Sara N ^a,b   Lavoie, Gino G ^a,c   Bergman, Robert G ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF NORTH CAROLINA   (United States)

^c EASTMAN CHEMICAL COMPANY   (United States)

Author keywords

Catalysis; Iridium; Planar chirality; Polymerization; Zirconium

Indexed keywords

ALIPHATIC COMPOUNDS; ANILINE; CATALYSIS; ELECTRON TRANSITIONS; ENANTIOMERS; ETHYLENE; IRIDIUM; LIGANDS; METAL COMPLEXES; POLYMERIZATION; POLYPROPYLENES; SYNTHESIS (CHEMICAL); TITANIUM COMPOUNDS; TRANSITION METALS; ZIRCONIUM;

CYCLOPENTADIENYL LIGANDS; CYCLOPENTADIENYL METAL COMPLEXES; DIASTEREO-SELECTIVITY; ISOTACTIC POLYPROPYLENE; PENTAMETHYLCYCLOPENTADIENYL; PLANAR CHIRALITY; REACTIVE SPECIES; ZIRCONIUM AND TITANIUM COMPLEXES;

ZIRCONIUM COMPOUNDS;

ALKYL GROUP; ANILINE DERIVATIVE; ETHYLENE; LIGAND; LITHIUM SALT; METAL COMPLEX; PHOSPHINE DERIVATIVE; POLYETHYLENE; TITANIUM DERIVATIVE; ZIRCONIUM DERIVATIVE;

ARTICLE; CATALYST; CHIRALITY; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; ENANTIOMER; LIGAND BINDING; METAL BINDING; POLYMERIZATION; PROTON TRANSPORT; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 1842578552     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)00742-9     Document Type: Article

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