Stereospecific CO insertion into the rhodium-methyl σ bond in [(Cp′-P)Rh(CO)(Me)]BF4 and deinsertion from [(Cp′-P)Rh(COMe)I]: Experimental evidence for methyl migration

Organometallics

Volumn 20, Issue 12, 2001, Pages 2431-2433

  Kataoka, Yasutaka ^a   Shibahara, Atsushi ^a   Yamagata, Tsuneaki ^a   Tani, Kazuhide ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL MIGRATION; METHYL MIGRATION; RHODIUM-METHYL BOND;

ALKYLATION; BENZENE; CARBON MONOXIDE; CHEMICAL BONDS; COMPLEXATION; CRYSTALLOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOCHEMISTRY; X RAY ANALYSIS;

ORGANOMETALLICS;

EID: 0035844914     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010143+     Document Type: Article

References (31)

1. For clear understanding, we define here several terms: "conversion of metal alkyl to metal acyl" means the net process of metal alkyl to metal acyl interconversion, which does not imply any stereochemistry at the metal center; "alkyl migration" or "retro-alkyl migration" means tthe stereospecific migration of alkyl to CO that leaves a vacant site at the position formerly occupied by the alkyl group or its reverse reaction; "CO insertion" or "retro-CO insertion" means the stereospecific insertion of CO into the metal-alkyl bond that leaves a vacant site at the position formerly occupied by CO or its reverse reaction.
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