Unique behavior of a (Ind-P)n ligand on the substitution reaction of {η5,η1-(Ind-P)n}RhCO with nBu3P

Chemistry Letters

Volumn , Issue 7, 1997, Pages 621-622

  Kataoka, Yasutaka ^a   Saito, Yoshinori ^a   Shibahara, Atsushi ^a   Tani, Kazuhide ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000694041     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.621     Document Type: Article

References (31)

1. For example, J. P. Collman, L. S. Hegedus, J. R. Norton, and R. G. Finke, "Principles and Applications of Organotransition Metal Chemistry" University Science Books: USA (1987).
2. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
3. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
4. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
5. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
6. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
7. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
8. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
9. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
10. C. Charrier and F. Mathey, J. Organomet. Chem., 170, C41 (1979); J. C. Leblanc, C. Moise, A. Maisonnat, R. Poilblanc, C. Charrier, and F. Mathey, J. Organomet. Chem. 231, C43 (1982); T. Kauffmann and J. Olbrich, Tetrahedron Lett., 25, 1967 (1984); A. M. Z. Slawin, D. J. Williams, J. Crosby, J. A. Ramsden, and C. White, J. Chem. Soc., Dalton Trans., 1988, 2491; R. T. Kettenbach and H. Butenschön, New. J. Chem., 14, 599 (1990); H. Butenschön, R. T. Kettenbach, and C. Krüger, Angew. Chem., Int. Ed. Engl., 31, 1066 (1992); R. T. Kettenbach, W. Bonrath, and H. Butenschön, Chem. Ber., 126, 1657 (1993); L. P. Barthel-Rosa, V. J. Catalano, and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629; L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, and J. H. Nelson, Organometallics, 15, 3924 (1996).
11. I. Lee, F. Dahan, A. Maisonnat, and R. Poilblanc, Organometallics, 13, 2743 (1994).
12. Y. Kataoka, Y. Saito, K. Nagata, K. Kitamura, A. Shibahara, and K. Tani, Chem. Lett., 1995, 833.
13. N. E. Schore and B. E. LaBelle, J. Org. Chem., 46, 2306 (1981); D. M. Bensley, Jr., E. A. Mintz, and S. J. Sussangkarn, J. Org. Chem., 53, 4417 (1988).
14. N. E. Schore and B. E. LaBelle, J. Org. Chem., 46, 2306 (1981); D. M. Bensley, Jr., E. A. Mintz, and S. J. Sussangkarn, J. Org. Chem., 53, 4417 (1988).
15. T. Kauffmann, J. Ennen, H. Lhotak, A. Rensing, F. Steinseifer, and A. Woltermann, Angew. Chem. Int. Ed. Engl., 19, 328 (1980).
16. n]H ligand.
17. C. F. Wilcox, Jr. and R. R. Craig, J. Am. Chem. Soc., 83, 3866 (1961).
18. K. Tani, K. Suwa, E. Tanigawa, T. Ise, T. Yamagata, Y. Tatsuno, and S. Otsuka, J. Organomet. Chem., 370, 203 (1989).
19. S. O. Grim and R. C. Barth, J. Organomet. Chem., 94, 327 (1975).
20. 25P: M, 356.1694.
21. 3 otherwise stated.
22. 20OPRh): C, H.
23. 24OPRh): C, H.
24. P. E. Garrou, Inorg. Chem., 14, 1435, (1975).
25. 3P).
26. M. E. Rerek, L.-N. Ji, and F. Basolo, J. Chem. Soc., Chem. Commun., 1983, 1208; M. E. Rerek and F. Basolo, Organometallics, 2, 372 (1983); M. E. Rerek and F. Basolo, J. Am. Chem. Soc., 106, 5908 (1984).
27. M. E. Rerek, L.-N. Ji, and F. Basolo, J. Chem. Soc., Chem. Commun., 1983, 1208; M. E. Rerek and F. Basolo, Organometallics, 2, 372 (1983); M. E. Rerek and F. Basolo, J. Am. Chem. Soc., 106, 5908 (1984).
28. M. E. Rerek, L.-N. Ji, and F. Basolo, J. Chem. Soc., Chem. Commun., 1983, 1208; M. E. Rerek and F. Basolo, Organometallics, 2, 372 (1983); M. E. Rerek and F. Basolo, J. Am. Chem. Soc., 106, 5908 (1984).
29. -1 (νCO).
30. c: 66.9 (dd, J = 3, 14 Hz), 94.9 (dd, J = 3, 6 Hz), 95.8 (dd, J = 3, 6 Hz).
31. F. H. Köhler, Chem. Ber., 107, 570 (1974).