New insight into structural and compositional variability in some ancient excess-Ca dolomite

Canadian Mineralogist

Volumn 43, Issue 4, 2005, Pages 1255-1290

  Drits, Victor A ^a,b   McCarty, Douglas K ^c   Sakharov, Boris ^a,b   Milliken, Kitty L ^c  

^a RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

^b UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^c CHEVRON ENERGY TECHNOLOGY COMPANY   (United States)

Author keywords

Computer simulation; Crystal chemistry; Dolomite; Electron microprobe data; Excess Ca dolomite; Rietveld refinement; X ray diffraction

Indexed keywords

CALCIUM COMPOUNDS; COMPOSITION; COMPUTER SIMULATION; CRYSTAL GROWTH; CRYSTAL STRUCTURE; MICROANALYSIS; SCANNING ELECTRON MICROSCOPY; X RAY POWDER DIFFRACTION;

COMPOSITIONAL VARIABILITY; CRYSTAL CHEMISTRY; DOLOMITE; ELECTRON-MICROPROBE ANALYSIS; RIETVELD REFINEMENT; STRUCTURAL VARIABILITY;

CARBONATE MINERALS;

CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; DOLOMITE; RIETVELD ANALYSIS;

EID: 29244466480     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.2113/gscanmin.43.4.1255     Document Type: Article

References (69)

1. 2, and its influence on the aragonite + magnesite ↔ dolomite reaction boundary. Am. Mineral. 89, 1142-1147.
2. Barber, D.J., Reeder, R.J. & Smith, D.J. (1985): A TEM microstructural study of dolomite with curved faces (saddle dolomite). Contrib. Mineral. Petrol. 91, 82-92.
3. Bergman, J. & Kleeberg, R. (1998): Rietveld analysis of disordered layer silicates. Materials Science Forum 278-281(1), 300-305.
4. Bergman, J., Kleeberg, R., Haase A. & Breidenstein, B. (2000): Advanced fundamental parameter model for improved profile analysis. Materials Science Forum 347-349(2), 303-308.
5. Blake, D.F., Peacor, D.R. & Wilkinson, B.H. (1982): The sequence and mechanism of low-temperature dolomite formation: calcian dolomite in a Pennsylvanian echinoderm. J. Sed. Petrol. 52, 59-70.
6. Bradley, W.F., Burst, J.F. & Graf, D.L. (1953): Crystal chemistry and differential thermal effects of dolomite. Am. Mineral. 38, 207-217.
7. Braunbarth, C., Hillhouse, H.W., Nair, S., Tsapatsis, M., Burton, A., Lobo, R.F., Jacubinas, R.M. & Kuznicki, S.M. (2000): Structure of strontium-ion-exchanged ETS-4 microporous molecular sieves. Chem. Materials 12, 1857-1865.
8. Budd, D.A. (1997): Cenozoic dolomites of carbonate islands: their attributes and origin. Earth-Sci. Rev. 42, 1-47.
9. Chai, L., Navrotsky, A. & Reeder, R.J. (1995): Energetics of calcium-rich dolomite. Geochim. Cosmochim. Acta 59, 939-944.
10. Cuadros, J. & Altaner, S.P. (1998): Compositional and structural features of the octahedral sheet in mixed-layer illite smectite from bentonites. Eur. J. Mineral. 10, 111-124.
11. Drits, V.A., Lanson, B., Gorshkov, A.I. & Manceau, A. (1998): Substructure and superstructure of four-layer Ca-exchanged birnessite. Am. Mineral. 83, 97-118.
12. Drits, V.A., Lanson, B., & McCarty, D.K. (1996): The nature of diffraction from illite and illite-smectite consisting of interstatified trans-vacant and cisvacant 2:1 layers: a semiquantitative technique determination of layer-type content. Am. Mineral. 81, 852-863.
13. Drits, V.A., & Sakharov, B.A. (1976): X-ray Structural Analysis of Mixed-Layer Minerals. Nauka, Moscow, Russia (in Russ.).
14. Drits, V.A., Środoń, J. & Eberl, D.D. (1997): XRD measurement of mean crystallite thickness of illite and illite/smectite: reappraisal of the Kubler index and the Scherrer equation. Clays Clay Minerals 45, 461-473.
15. Drits, V.A., & Tchoubar, C. (1990): X-ray Diffraction of Disordered Lamellar Structures. Theory and Application to Microdivided Silicates and Carbons. Springer Verlag, New York, N.Y.
16. Drits, V.A., Weber, F., Salyn, A.L. & Tsipursky, S.I. (1993): X-ray identification of 1M illite varieties. Clays Clay Minerals 41, 389-398.
17. Effenberger, H., Mereiter, K. & Zemann, J. (1981): Crystal structure refinements of magnesite, calcite, rhodochosite, siderite, smithsonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite-type carbonates. Z. Kristallogr. 156, 233-243.
18. Fouke, B.W. & Reeder, R.J. (1992): Surface structural controls on dolomite composition: evidence from sectoral zoning. Geochim. Cosmochim. Acta 56, 4015-4024.
19. Füchtbauer, H. & Goldsmith, J.R. (1965): Beziehungen zwischen Calciumgehalt und Bildungs-bedingungen der Dolomite. Geol. Rundschau 55, 29-40.
20. 4. 2. Phase and structural heterogeneities. Chem. Materials 16, 1890-1905.
21. Goldsmith, J.R. & Graf, D.L. (1958): Structural and compositional variations in some natural dolomites. J. Geol. 66, 678-693.
22. Graf, D.L. (1961): Crystallographic tables for the rhombohedral carbonates. Am. Mineral. 46, 1283-1316.
23. Graf, D.L. (1969): Crystallographic tables for the rhombohedral carbonates: a correction. Am. Mineral. 54, 325.
24. Graf, D.L., Blyth, C.R. & Stemmler, R.S. (1967): One-dimensional disorder in carbonates. Illinois State Geol. Surv., Circ. 408, 1-60.
25. Gregg, J.M., Howard, S.A & Mazzullo, S.J. (1992): Early diagenetic recrystallization of Holocene (<3000 years old) peritidal dolomites, Ambergris Cay, Belize. Sedimentology 39, 143-160.
26. Gualtieri, A.F. (1999): Modeling the nature of disorder in talc by simulation by X-ray powder diffraction. Eur. J. Mineral. 11, 521-532.
27. Guinier, A. (1964): Theorie et technique de la radiocristallographie. Chap 13: Diffraction par les réseaux cristallins imparfaits. Dunod, Paris, France (490-636).
28. Howie, R.A. & Broadhurst, F.M. (1958): X-ray data for dolomite and ankerite. Am. Mineral. 43, 1210-1214.
29. Jones, B., Luth, R.W. & MacNeil, A.J. (2001): Powder X-ray diffraction analysis of homogeneous and heterogeneous sedimentary dolostones. J. Sedimen. Res. 71, 790-799.
30. Land, L.S. (1980): The isotopic and trace element geochemistry of dolomite: the state of the art. In Concepts and Model of Dolomitization (D.H. Zenger, J.B. Dunham & R.L. Ethington, eds.). Soc. Econ. Geol., Paleontol., Mineral., Spec. Publ. 28, 87-110.
31. Lanson, B., Drits, V.A., Gaillot, A.-C., Silvester, E., Plançon, A. & Manceau, A. (2002): Structure of heavy metal sorbed birnessite. I. Results from X-ray diffraction. Am. Mineral. 87, 1631-1645.
32. Lanson, B., Drits, V.A., Silvester, E. & Manceau, A. (2000): Structure of H-exchanged hexagonal birnessite and its mechanism of formation from Na-rich monoclinic buserite at low pH. Am. Mineral. 85, 826-838.
33. Leoni, M, Gualtieri, A.F. & Roveri, N. (2004): Simultaneous refinement of structure and microstructure of layered materials. J. Appl. Crystallogr. 37, 166-173.
34. Lippmann, F. (1973): Sedimentary Carbonate Minerals. Springer-Verlag, Berlin, Germany.
35. Lumsden, D.N. (1979): Discrepancy between thin-section and X-ray estimates of dolomite in limestones. J. Sed. Petrol. 49, 429-436.
36. 2+ oxidation by the phyllomanganate buserite. Am. Mineral. 82, 1150-1175.
37. Manceau, A., Lanson, B., Drits, V.A., Chateigner, D., Gates, W.P., Wu, J., Huo, D. & Stucki, J.W. (2000): Oxidation-reduction mechanism of iron in dioctahedral smectites. I. Crystal chemistry of oxidized reference nontronites. Am. Mineral. 85, 133-152.
38. Mazzullo, S.J. (1992): Geochemical and neomorphic alteration of dolomite: a review. Carbonates and Evaporites 7, 21-37.
39. McCarty, D.K. & Reynolds, R.C., Jr. (1995): Rotationally disordered illite smectite in Paleozoic K-bentonites. Clays Clay Minerals 43, 271-284.
40. McCarty, D.K. & Reynolds, R.C., Jr. (2001): Three-dimensional crystal structures of illite-smectite minerals in Paleozoic K-bentonites from the Appalachian basin. Clays Clay Minerals 49, 24-35.
41. Méring, J. (1949): L'interférence des rayons X dans les systèmes à stratification désordonnée. Acta Crystallogr. 2, 371-377.
42. Miser, D.E., Swinnea, J.S. & Steinfink, H. (1987): TEM observations and X-ray crystal-structure refinement of a twinned dolomite with a modulated structure. Am. Mineral. 72, 188-193.
43. Navrotsky, A. & Capobianco, C. (1987): Enthalpies of formation of dolomite and of magnesian calcite. Am. Mineral. 72, 782-787.
44. Newsam, J.M. & Treacy, M.M.J. (1993): ZeoFile: a stack of zeolite structure types. Zeolites 13, 183-186.
45. Plançon, A. (1981): Diffraction by layer structures containing different kinds of layers and stacking faults. J. Appl. Crystallogr. 14, 300-304.
46. Plançon, A. (2002): New modeling of X-ray diffraction by disordered lamellar structures, such as phyllosilicates. Am. Mineral. 87, 1672-1677.
47. Plançon, A., Giese, R.F., Snyder, R., Drits, V.A. & Bookin, A.S. (1989): Stacking faults in the kaolin-group minerals: defect structures of kaolinite. Clays Clay Minerals 37, 203-210.
48. Plançon, A. & Tchoubar, C. (1977): Determination of structural defects in phyllosilicates by X-ray powder diffraction. I. Principle of calculation of the diffraction phenomenon. Clays Clay Minerals 25, 430-435.
49. Reeder, R.J. (1981): Electron optical investigation of sedimentary dolomites. Contrib. Mineral. Petrol. 76, 148-157.
50. Reeder, R.J. (1983): Crystal chemistry of the rhombohedral carbonates. In Carbonates; Mineralogy and Chemistry (R.J. Reeder, ed.). Rev. Mineral. 11, 1-47.
51. Reeder, R.J. (1992): Carbonates; growth and alteration micro-structures. In Minerals and Reactions at the Atomic Scale; High Resolution Transmission Electron Microscopy (P.R. Buseck, ed.). Rev. Mineral. 27, 380-424.
52. Reeder, R.J. (2000): Constraints on cation order in calcium-rich sedimentary dolomite. Aquatic Geochem. 6, 213-226.
53. Reeder, R.J. & Dollase, W.A. (1989) Structural variation in the dolomite-ankerite solid-solution series: an X-ray, Mössbauer, and TEM study. Am. Mineral. 74, 1159-1167.
54. Reeder, R.J. & Wenk, H.-R. (1979): Microstructures in low temperature dolomites. Geophys. Res. Lett. 6, 77-80.
55. Reeder, R.J. & Wenk, H.-R. (1983): Structure refinements of some thermally disordered dolomites. Am. Mineral. 68, 769-776.
56. Reksten, K. (1990): Superstructures in calcian ankerite. Phys. Chem. Minerals 17, 266-270.
57. Reynolds, R.C., Jr. (1993): Three-dimensional X-ray powder diffraction from disordered illite: simulation and interpretation of the diffraction patterns. In Computer Applications to X-Ray Diffraction Analysis of Clay Minerals (R.C. Reynolds Jr. & J.R. Walker, eds.). Clay Minerals Soc., Workshop Lectures 5, 43-78.
58. Rietveld, H. (1969): A profile refinement method for nuclear and magnetic structures. J. Appl. Crystallogr. 2, 65-71.
59. Sakharov, B.A., Besson, G., Drits, V.A., Kameneva, M.Y., Salyn, A.L. & Smoliar, B.B. (1990): X-ray study of the nature of stacking faults in the structure of glauconites. Clay Minerals 25, 419-435.
60. Sakharov, B.A., Naumov, A.S. & Drits, V.A. (1982): X-ray diffraction by mixed-layer structures with random distribution of stacking faults. Dokl. Akad. Nauk SSSR 265, 339-343 (in Russ.).
61. Searl, A. (1994): Discontinuous solid solution in Ca-rich dolomites: the evidence and implications for the interpretation of dolomite petrographic and geochemical data. In Dolomites: a Volume in Honour of Dolomieu (B. Purser, ed.). Int. Assoc. Sedimentol., Spec. Publ. 21, 361-376.
62. Searl, A. & Fallick, A.E. (1990): Dinantian dolomites from East Fife: hydrothermal overprinting of early mixing zone stable isotopic and Fe/Mn compositions. J. Geol. Soc. London 147, 623-638.
63. Sperber, C.M., Wilkinson, B.H. & Peacor, D.R. (1984): Rock composition, dolomite stoichiometry and rock/water reactions in dolomitic carbonate rocks. J. Geol. 92, 609-622.
64. Steinfink, H. & Sans, F.J. (1959): Refinement of the crystal structure of dolomite. Am. Mineral. 44, 679-682.
65. Van Tendeloo, G., Wenk, H.-R. & Gronsky, R. (1985): Modulated structures in calcian dolomite: a study by electron microscopy. Phys. Chem. Minerals 12, 333-341.
66. Wenk, H.-R., Barber, D.J. & Reeder, R.J. (1983): Micro-structures in carbonates. In Carbonates: Mineralogy and Chemistry (R.J. Reeder, ed.). Rev. Mineral. 11, 301-367.
67. Wenk, H.-R., Hu, Meisheng, Lindsey, T. & Morris, H.W., Jr. (1991): Superstructures in ankerite and calcite. Phys. Chem. Minerals 17, 527-539.
68. Wenk, H.-R., Zhang, F. (1985): Coherent transformations in calcian dolomites. Geology 13, 457-460.
69. Ylagan, R.F., Altaner, S.P. & Pozzuoli, A. (2000): Reaction mechanisms of smectite illitization associated with hydrothermal alteration from Ponza Island, Italy. Clays Clay Minerals 48, 610-631.