Solvent polarization and kinetic isotope effects in nitroethane deprotonation and implications to the nitroalkane oxidase reaction

Journal of the American Chemical Society

Volumn 127, Issue 47, 2005, Pages 16374-16375

  Major, Dan T ^a   York, Darrin M ^a   Gao, Jiali ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHANE; ISOTOPE; NITROALKANE OXIDASE; NITROETHANE; OXIDOREDUCTASE; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CATALYSIS; CHEMICAL REACTION; DEPROTECTION REACTION; ENZYME MECHANISM; HYDROGEN BOND; KINETICS; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR STABILITY; POLARIZATION; QUANTUM MECHANICS; REACTION ANALYSIS; SIMULATION;

COMPUTER SIMULATION; DEUTERIUM; DIOXYGENASES; ETHANE; KINETICS; NITROPARAFFINS; PROTONS; SOLVENTS; THERMODYNAMICS; WATER;

EID: 28444447058     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja055881u     Document Type: Article

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