Experimental evidence for γ-agostic assistance in β-methyl elimination, the microscopic reverse of α-agostic assistance in the chain propagation step of olefin polymerization

Organometallics

Volumn 24, Issue 11, 2005, Pages 2789-2794

  Chirik, Paul J ^a,b   Dalleska, Nathan F ^a   Henling, Lawrence M ^a   Bercaw, John E ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; HYDROCYCLIZATION; METALLOCENES; TRANSITION STATE;

CARBON; CATALYSTS; CHEMICAL BONDS; DEUTERIUM; GROUND STATE; ISOTOPES; POLYMERIZATION; TOPOLOGY;

OLEFINS;

EID: 20444487398     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om058002l     Document Type: Article

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