Mechanistic aspects of formation of chiral ruthenium hydride complexes from 16-electron ruthenium amide complexes and formic acid: Facile reversible decarboxylation and carboxylation

Advanced Synthesis and Catalysis

Volumn 346, Issue 1, 2004, Pages 37-41

  Koike, Takashi ^a   Ikariya, Takao ^a  

^a Tokyo Institute of Technology ^*  (Japan)

Author keywords

Carbon dioxide insertion; Decarboxylation; M NH bifunctional effect; Ruthenium formate; Ruthenium hydride

Indexed keywords

AMIDE; FORMIC ACID; RUTHENIUM COMPLEX;

ARTICLE; CARBOXYLATION; CHEMICAL REACTION; CHIRALITY; DECARBOXYLATION; ELECTRON; PRESSURE;

EID: 1642445655     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200303152     Document Type: Article

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48. 2 in the presence of N′,N′-dimethylammonium N,N-dimethylcarbamate as substrate (S/C = 1,000) at 50°C for 45 h to give DMF in moderate yield, 69% yield.
49. 2 in the presence of N′,N′-dimethylammonium N,N-dimethylcarbamate as substrate (S/C = 1,000) at 50°C for 45 h to give DMF in moderate yield, 69% yield.