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2342633585
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note
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The in-depth photophysical studies including time-resolved absorption will be reported elsewhere.
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24
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27
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84991138979
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ΔG values (kJ/mol) were obtained for triad 1 (-182.11), triad 2 (-178.25), triad 3 (-177.28), triad 4 (-178.24), triad 5 (-180.18) and triad 6 (-178.25) respectively estimated by Rehm-Weller equation according to the reference: Rehm, D.; Weller, D. Isr. J. Chem. 1970, 8, 259.
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28
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2342625756
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note
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The different photophysical behaviors between triads 1-6 may be due to their difference in spatial separation between TTF and NI units: 2.5 nm for 1 and 2; 1.2 nm for 3, 4, 5 and 6. The spatial distances between TTF and NI units were estimated by semiempirical AM1 method with Ampec 6.7 program.
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29
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0038176318
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Guo, X.-F.; Zhang, D.-Q.; Zhang, H.-J.; Fan, Q.-H.; Xu, W.; Ai, X.-C.; Fan, L.-Z.; Zhu, D.-B. Tetrahedron 2003, 59, 4843.
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Zhu, D.-B.8
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30
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2342487132
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note
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As the cross-sectional area of the side chains of the molecule increases, greater steric repulsion between adjacent side chains could possibly cause a reduction in π-π interaction among TTF themselves in order to relieve the repulsive forces.
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32
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0002129645
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Steimecke, G.1
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Hoyer, E.4
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