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Volumn 22, Issue 3, 2004, Pages 296-305

Synthesis and Characterization of Donor-Acceptor-Donor Triads Containing Tetrathiafulvalene and Naphthalene Diimide Units: Towards Regulation of the Intermolecular Charge-Transfer Interaction by Varying the Attached Side Groups

Author keywords

Charge transfer interaction; Naphthalene diimide; Photoinduced electron transfer; Tetrathiafulvalene

Indexed keywords

NAPHTHALENE DERIVATIVE; TETRATHIAFULVALENE DERIVATIVE;

EID: 2342466612     PISSN: 1001604X     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjoc.20040220317     Document Type: Article
Times cited : (7)

References (32)
  • 1
    • 2342621883 scopus 로고
    • Eds.: Yoshida, Z.; Shiba, T.; Ohshiro, Y. Koda Nsha, Tokyo, 1989; VCH, Weinheim-New York-Cambrige-Basel
    • (a) Staab, H. A. In New Aspect of Organic Chemistry I, Eds.: Yoshida, Z. ; Shiba, T.; Ohshiro, Y. Koda Nsha, Tokyo, 1989; VCH, Weinheim-New York-Cambrige-Basel, 1989, pp. 227-236.
    • (1989) New Aspect of Organic Chemistry I , pp. 227-236
    • Staab, H.A.1
  • 23
    • 2342633585 scopus 로고    scopus 로고
    • note
    • The in-depth photophysical studies including time-resolved absorption will be reported elsewhere.
  • 27
    • 84991138979 scopus 로고
    • ΔG values (kJ/mol) were obtained for triad 1 (-182.11), triad 2 (-178.25), triad 3 (-177.28), triad 4 (-178.24), triad 5 (-180.18) and triad 6 (-178.25) respectively estimated by Rehm-Weller equation according to the reference: Rehm, D.; Weller, D. Isr. J. Chem. 1970, 8, 259.
    • (1970) Isr. J. Chem. , vol.8 , pp. 259
    • Rehm, D.1    Weller, D.2
  • 28
    • 2342625756 scopus 로고    scopus 로고
    • note
    • The different photophysical behaviors between triads 1-6 may be due to their difference in spatial separation between TTF and NI units: 2.5 nm for 1 and 2; 1.2 nm for 3, 4, 5 and 6. The spatial distances between TTF and NI units were estimated by semiempirical AM1 method with Ampec 6.7 program.
  • 30
    • 2342487132 scopus 로고    scopus 로고
    • note
    • As the cross-sectional area of the side chains of the molecule increases, greater steric repulsion between adjacent side chains could possibly cause a reduction in π-π interaction among TTF themselves in order to relieve the repulsive forces.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.