Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and μ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)-OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)-OH

Chemical Communications

Volumn , Issue 9, 1998, Pages 1005-1006

  Akita, Munetaka ^a   Miyaji, Taichi ^a   Hikichi, Shiro ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003089467     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a801111g     Document Type: Article

References (17)

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5. Metal-Dioxygen Complexes, Chem. Rev., 1994, 94, 567.
6. N. Kitajima and Y. Moro-oka, Chem. Rev., 1994, 94, 737;
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8. see also, S. Trofimenko, Chem. Rev., 1993, 93, 943.
9. (a) Co: S. Hikichi, H. Komatsuzaki, N. Kitajima, M. Akita, M. Mukai, T. Kitagawa and Y. Moro-oka, Inorg. Chem., 1997, 36, 266;
10. (b) Rh: M. Akita, K. Ohta, Y. Takahashi, S. Hikichi and Y. Moro-oka, Organometallics, 1997, 16, 4121;
11. (c) Y. Takahashi, M. Hashimoto, S. Hikichi, M. Akita and Y. Moro-oka, unpublished work;
12. (d) Ru: Y. Takahashi, M. Akita, S. Hikichi and Y. Moro-oka, Inorg. Chem., in press.
13. N. Kitajima, T. Katayama, K. Fujisawa, Y. Iwata and Y. Moro-oka, J. Am. Chem. Soc., 1993, 115, 7872;
14. N. Kitajima, H. Komatsuzaki, S. Hikichi, M. Osawa and Y. Moro-oka, J. Am. Chem. Soc., 1994, 116, 11596;
15. S. Hikichi, H. Komatsuzaki, M. Akita and Y. Moro-oka, J. Am. Chem. Soc., in press.
16. 4 [O-O 1.49 Å; mean Pd-O 1.994(3) Å], was reported: H. Mimoun, R. Charpentier, A. Mitschler, J. Fischer and R. Weiss, J. Am. Chem. Soc., 1980, 102, 1047.
17. 2 [O-Q 1.37(2) Å, Pd-O 2.051(14), 2.057(12) Å] was also reported: T. Yoshida, K. Tatsumi, M. Matsumoto, K. Nakatsu, A. Nakamura, T. Fueno and S. Otsuka, Nouv. J. Chim., 1979, 3, 761.