Synthesis and dehydrative condensation of square-planar mono- and dinuclear hydroxopalladium complexes with the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr)2), Tp(iPr)2(Py)Pd-OH, and (μ-OH)2{PdTp(iPr)2(H2O)}2

Inorganic Chemistry

Volumn 39, Issue 10, 2000, Pages 2096-2102

  Akita, Munetaka ^a   Miyaji, Taichi ^a   Muroga, Nobuyuki ^a   Mock Knoblauch, Cordula ^a   Adam, Waldemar ^a   Hikichi, Shiro ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ACETOACETIC ACID DERIVATIVE; CHLORIDE; FUNCTIONAL GROUP; HYDROGEN; HYDROXYL GROUP; LIGAND; NITROGEN; PALLADIUM COMPLEX; PYRAZOLE DERIVATIVE; WATER;

ARTICLE; CRYSTAL STRUCTURE; DESICCATION; HYDROGEN BOND; HYDROLYSIS; POLYMERIZATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0034656730     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic991034e     Document Type: Article

References (14)

1. (a) Bryndza, H. E.; Tam, W. Chem. Rev. 1988, 88, 1163.
2. (b) Gilje, J. W.; Roesky, H. W. Chem. Rev. 1994, 94, 895.
3. (a) Trofimenko, S. Chem. Rev. 1993, 93, 943.
4. (b) Kitajima, N.; Tolman, W. B. Prog. Inorg. Chem. 1995, 43, 419.
5. (c) Kitajima, N.; Moro-oka, Y. Chem. Rev. 1994, 94, 737.
6. (d) Trofimenko, S. Scorpionates The Coordination Chemistry of Polypyrazolylborate Ligands', Imperial College Press: London, England, 1999.
7. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
8. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
9. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
10. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
11. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
12. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
13. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.
14. Rx ligand. (a) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 1005. (b) Akita, M.; Miyaji, T.; Hikichi, S.; Moro-oka, Y. Chem. Lett. 1999, 813. (c) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121. (d) Ohta, K.; Hashimoto, M.; Takahashi, Y.; Hikichi, S.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3234. (e) Takahashi, Y.; Akita, M.; Hikichi, S.; Moro-oka, Y. Organometallics 1998, 17, 4884. References 3f-3h are reviews. (f) Akita, M.; Hikichi, S.; Moro-oka, Y. J. Synth. Org. Chem. 1999, 57, 619. (g) Hikichi, S.; Akita M., Moro-oka, Y. Coord. Chem. Rev., in press. (h) See also references cited in ref 3d.