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Volumn 118, Issue 20, 1996, Pages 4846-4852

Reactivity of platinum - Oxygen bonds: Kinetic and mechanistic studies of the carbonylation of platinum aryloxide complexes and the formation of (aryloxy)carbonyls

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM COMPLEX;

EID: 0029890191     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952680p     Document Type: Article
Times cited : (44)

References (53)
  • 32
    • 0038260823 scopus 로고
    • Moser. W. R., Slocum, D. W., Eds.; Advances in Chemistry Series; American Chemical Society: Washington, D C
    • Ni, J.; Kubiak, C. P. In Homogeneous Transition Metal Catalyzed Reactions; Moser. W. R., Slocum, D. W., Eds.; Advances in Chemistry Series; American Chemical Society: Washington, D C, 1992; Vol. 230, pp 515-528.
    • (1992) Homogeneous Transition Metal Catalyzed Reactions , vol.230 , pp. 515-528
    • Ni, J.1    Kubiak, C.P.2
  • 41
    • 0000799793 scopus 로고
    • Although first prepared in 1971 by King et. al. (Inorg. Chem. 1971, 10, 1841-50). this synthesis requires less time. The yields are similar to the earlier preparation and give a product spectroscopically identical to that reported for [Pt(triphos)(Cl)][Cl].
    • (1971) Inorg. Chem. , vol.10 , pp. 1841-1850
    • King1
  • 42
    • 85033866889 scopus 로고    scopus 로고
    • note
    • 1H NMR.
  • 43
    • 85033847973 scopus 로고    scopus 로고
    • note
    • Ambient room temperature in the NMR probe is ca. 22 °C. During the reaction the NMR tube was not removed from the probe. Due to probe design, the probe cooling air provides a thermostatic environment. Experiments with the NMR chemical shift thermometer have shown that the probe temperature would vary by less than ±1 °C over the length of the experiment. Sample heating during the actual NMR experiment, due to decoupling, should be minimal as low power WALTZ decoupling was used.
  • 53
    • 85033869051 scopus 로고    scopus 로고
    • note
    • obs = 5.16σ + 2.20.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.