Stoichiometric and catalytic demercuration of bis(tricarbido)mercurials: The first dimetallaoctatetraynes

Organometallics

Volumn 24, Issue 13, 2005, Pages 3043-3046

  Dewhurst, Rian D ^a   Hill, Anthony F ^a   Willis, Anthony C ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CATALYSIS; CHEMICAL BONDS; CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; STOICHIOMETRY; SYNTHESIS (CHEMICAL); TRANSITION METALS;

BIS(TRICARBIDO)MERCURIALS; CATALYTIC DEMERCURATION; DIMETALLAOCTATETRAYNES; LIGANDS;

MERCURY COMPOUNDS;

EID: 23144450389     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om058011u     Document Type: Article

References (51)

1. n complexes, respectively, see: (a) Low, P. J.; Bruce, M. I. Adv. Organomet. Chem. 2002, 48, 71.
2. (b) Bruce, M. I.; Low, P. J. Adv. Organomet. Chem. 2004, 50, 179.
3. (a) Dewhurst, R. D.; Hill, A. F.; Smith, M. K. Angew. Chem., Int. Ed. 2004, 43, 476.
4. (b) Dewhurst, R. D.; Hill, A. F.; Willis, A. C. Organometallics 2004, 23, 1646.
5. (c) Dewhurst, R. D.; Hill, A. F.; Willis, A. C. Organometallics 2004, 23, 5903.
6. (d) Dewhurst, R. D.; Hill, A. F.; Willis, A. C. Chem. Commun. 2004, 2826.
7. (a) Weng, W.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 3824.
8. (b) Bartik, T.; Weng, W.; Ramsden, J. A.; Szafert, S.; Falloon, S. B.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1998, 120, 11071.
9. (c) Deminski, R.; Szafert, S.; Haquette, P.; Lis, T.; Gladysz, J. A. Organometallics 1999, 18, 5438.
10. Woodworth, B. E.; Templeton, J. L. J. Am. Chem. Soc. 1996, 118, 7418.
11. Collman, J. P.; Kang, J. W. J. Am. Chem. Soc. 1967, 89, 844.
12. Seyferth, D.; Ruschke, D. P.; Davis, W. M.; Cowie, M.; Hunter, A. D. Organometallics 1994, 13, 3834.
13. Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Wilkinson, D. A. J. Organomet. Chem. 1991, 408, C9.
14. Fontain, X. L. R.; Higgins, S. J.; Langrick, C. R.; Shaw, B. L. J. Chem. Soc., Dalton Trans. 1987, 777.
15. Dauter, Z.; Mawby, R. J.; Reynolds, C. D.; Saunders: D. R. J. Chem. Soc., Dalton Trans. 1986, 433.
16. (a) Cross, R. J.; Davidson, M. F. J. Chem. Soc., Dalton Trans. 1986, 1987.
17. (b) Cross, R. J.; Davidson, M. F. Inorg. Chim. Acta 1985, 97, L35.
18. (c) Cross, R. J.; Gemmill, J. J. Chem. Soc., Chem. Commun. 1982, 1343.
19. Deacon, G. B.; Wilkinson, D. L. Inorg. Chim. Acta 1988, 142, 155.
20. Lin, G.; McDonald, R.; Takats, J. Organometallics 2000, 19, 1814.
21. (a) Hill, A. F.; Wilton-Ely, J. D. E. T. Organometallics 1997, 16, 4517.
22. (b) Hill, A. F.; Harris, M. C. J.; Melling, R. P. Polyhedron 1992, 11, 781.
23. (c) Hill, A. F.; Melling, R. P. J. Organomet. Chem. 1990, 396, C22.
24. Bedford, R. B.; Hill, A. F.; Thompsett, A. R.; White, A. J. P.; Williams, D. J. J. Chem. Soc., Chem. Commun. 1996, 1059.
25. Siemsen, P.; Livingston, R. C.; Diederich, F.Angew. Chem., Int. Ed. 2000, 39, 2632.
26. (a) Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5889.
27. (b) Owen, G. R.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5893.
28. (c) Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 3324.
29. (d) Meyer, W. E.; Amoroso, A. J.; Horn, C. R.; Jaeger, M.; Gladysz, J. A. Organometallics 2001, 20, 1115.
30. (e) Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810.
31. (f) Brady, M.; Weng, W.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1994, 23, 2655.
32. Bruce, M. I.; Hall, B. C.; Kelly, B. D.; Low, P. J.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1999, 3719.
33. Sakurai, A.; Akita, M.; Moro-oka, Y. Organometallics 1999, 18, 3241.
34. Wong, W.-Y.; Wong, C.-K.; Lu, G.-L.; Cheah, K.-W.; Shi, J.-X.; Lin, Z. Dalton 2002, 4587.
35. Lu, W.; Xiang, H.-F.; Zhu, N.; Che, C.-M. Organometallics 2002, 21, 2343.
36. - increases the atom efficiency with respect to "C≡CR" transfer.
37. -1, T = 200 K, green plate, 7108 independent measured reflections (20 < 55°), R1 = 0.0219, wR2 = 0.0259 for 4734 independent observed absorption-corrected reflections (I > 3σ(I)), 360 parameters. CCDC 264360.
38. Hart, I. J.; Hill, A. F.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1989, 2261.
39. One indication of deviation from net linearity is given by the sum of bond lengths along the chain: cf. the distance between metals. In the case of 2a this is within the limits of experimental uncertainty (0.020(33) Å).
40. Anderson, S.; Cook, D. J.; Hill, A. F.; Malget, J. M.; White, A. J. P.; Williams, D. J. Organometallics 2004, 23, 2552 and references therein.
41. (a) Listemann, M. L.; Schrock, R. R. Organometallics 1985, 4, 74.
42. (b) Caulton, K. G.; Cayton, R. H.; Chisholm, M. H.; Huffman, J. C.; Lobkovsky, E. B.; Xue, Z. Organometallics 1992, 11, 321.
43. (c) Gilbert, T. M.; Rogers, R. D. J. Organomet. Chem. 1991, 421, C1.
44. Woodworth, B. E.; White, P. S.; Templeton, J. L. J. Am. Chem. Soc. 1998, 120, 9028.
45. Woodworth, B. E.; White, P. S.; Templeton, J. L. J. Am. Chem. Soc. 1997, 119, 828.
46. Jamison, G. M.; Bruce, A. E.; White, P. S.; Templeton, J. L. J. Am. Chem. Soc. 1991, 113, 5057.
47. Woodworth, B. E.; Frohnapfel, D. S.; White, P. S.; Templeton, J. L. Organometallics 1998, 17, 1655.
48. Jeffery, J. C.; Stone, F. G. A.; Williams, G. K. Polyhedron 1991, 10, 215.
49. Filippou, A. C.; Wagner, C.; Fischer, E. O.; Voelkl, C. J. Organomet. Chem. 1992, 438, C15.
50. Stone, K. C.; White, P. S.; Templeton, J. L. J. Organomet. Chem. 2003, 684, 13.
51. Schwenzer, B.; Schleu, J.; Burzlaff, N.; Karl, C.; Fischer, H. J. Organomet. Chem. 2002, 641, 134.