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3743066778
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note
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12Sm: C, 53.96; H, 5.84; N, 19.87. Found: C, 52.15; H, 5.60; N, 19.57.
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14
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85088331615
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note
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3, Z = 2, T = -60°C, R1 = 0.0559, wR2 = 0.1563, GOF = 1.046. For further details, see the Supporting Information.
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15
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3743105714
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note
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8 between 60 and -100 °C showed no change except for the temperature dependence of the chemical shifts; plots of chemical shifts versus 1/T were linear, consistent with simple Curie-Weiss behavior. These observations indicate that the simple, monomeric solid-state structure is maintained in solution and that the molecular rearrangement which renders the pyrazolyl groups equivalent has a low activation barrier.
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16
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0001211170
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19
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3743099111
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note
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1/2 = 220 Hz).
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20
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3743125867
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note
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3, Z = 2, T = -60°C, R1 = 0.0660, wR2 = 0.1551, GOF = 1.048. For further details, see the Supporting Information.
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85088333180
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note
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3.
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34
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85088333191
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note
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13b
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