Determination of pesticides and PCBs in virgin olive oil by multicolumn solid-phase extraction cleanup followed by GC-NPD/ECD and confirmation by ion-trap GC-MS

Journal of Agricultural and Food Chemistry

Volumn 53, Issue 13, 2005, Pages 5105-5109

  Yagüe, Cristina ^a   Bayarri, Susana ^a   Conchello, Pilar ^a   Lázaro, Regina ^a   Pérez Arquillué, Consuelo ^a   Herrera, Antonio ^a   Ariño, Agustín ^a  

^a UNIVERSIDAD DE ZARAGOZA   (Spain)

Author keywords

Capillary gas chromatography mass spectrometric detection; Organochlorine pesticides; Organophosphorus pesticides; Polychlorinated biphenyls; Virgin olive oil

Indexed keywords

CHLORINATED HYDROCARBON; OLIVE OIL; ORGANOPHOSPHORUS COMPOUND; PESTICIDE; POLYCHLORINATED BIPHENYL; VEGETABLE OIL;

ARTICLE; CHEMISTRY; GAS CHROMATOGRAPHY; MASS FRAGMENTOGRAPHY; METHODOLOGY; QUALITY CONTROL; SENSITIVITY AND SPECIFICITY;

CHROMATOGRAPHY, GAS; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HYDROCARBONS, CHLORINATED; ORGANOPHOSPHORUS COMPOUNDS; PESTICIDES; PLANT OILS; POLYCHLORINATED BIPHENYLS; QUALITY CONTROL; SENSITIVITY AND SPECIFICITY;

EID: 22244469422     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf050247l     Document Type: Article

References (23)

1. Ministry of Agriculture, Fisheries and Food. The Spanish Agrofood Sector and Rural Environment: Facts and Figures, 6th ed.; MAPA, Technical Secretariat General: Madrid, Spain, 2002.
2. Morelló, J. R.; Motilva, M. J.; Tovar, M. J.; Romero, M. P. Changes in commercial virgin olive oil (cv Arbequina) during storage, with special emphasis on the phenolic fraction. Food Chem. 2004, 85, 357-364.
3. Lentza-Rizos, Ch. Monitoring pesticide residues in olive products: Organophosphorus insecticides in olives and oil. J. AOAC Int. 1994, 77, 1096-1100.
4. Sannino, A.; Mambriani, P.; Bandini, M.; Bolzoni, L. Multiresidue Method for Determination of Organochlorine Insecticides and Polychlorinated Biphenyl Congeners in Fatty Processed Foods. J. AOAC Int. 1996, 79, 1434-1446.
5. Hiskia, A. E.; Atmajidou, M. E.; Tsipi, D. F. Determination of Organophosphorus Pesticide Residues in Greek Virgin Olive Oil by Capillary Gas Chromatography. J. Agric. Food Chem. 1998, 46, 570-574.
6. Cavanna, S.; Molinari, G. P. Residues of fenthion and trichlorofon in olives and olive oil after olive tree treatments. Food Addit. Contam. 1998, 15, 518-527.
7. Lentza-Rizos, Ch.; Avramides, E. J.; Visi, E. Determination of residues of endosulfan and five pyrethroid insecticides in virgin olive oil using gas chromatography with electron-capture detection. J. Chromatogr., A 2001, 921, 297-304.
8. Sanchez, R.; Vazquez, A.; Andini, J. C.; Villen, J. Automated multiresidue analysis of pesticides in olive oil by on-line reversed-phase liquid chromatography - gas chromatography using the through oven trsnsfer adsorption-desoption interface. J. Chromatogr., A 2004, 1029, 167-172.
9. Association of Official Analytical Chemists. Official methods of analysis of AOAC International, 16th ed.; AOAC: Arlington, VA, 1995; Chapter 10.
10. Botitsi, E.; Kormali, P.; Kontou, S.; Mourkojanni, A.; Stavrakaki, E.; Tsipi, D. Monitoring of pesticide residues in olive oil samples: results and remarks between 1999 and 2002. Int. J. Environ. Anal. Chem. 2004, 84, 231-239.
11. Vreuls, J. J.; Swen, R. J.; Goudriaan, V. P.; Kerkhoff, M. A.; Jongenotter, G. A.; Brinkman, U. A. Automated on-line gel permeation chromatography - gas chromatography for the determination of organophosphorus pesticides in olive oil. J. Chromatogr., A 1996, 750, 275-286.
12. Niessner, G.; Buchberger, W.; Eckerstorfer, R. Multiresidue screening methods for the determination of pesticides in plant materials. J. Chromatogr., A 1999, 846, 341-348.
13. Tsatsakis, A. M.; Tsakiris, I. N.; Tzatzarakis, M. N.; Agourakis, Z. B.; Tutudaki, M.; Alegakis, A. K. Three-year study of fenthion and dimethoate pesticides in olive oil from organic and conventional cultivation. Food Addit. Contam. 2003, 20, 553-559.
14. Cabras, P.; Angioni, A.; Melis, M.; Minelli, E. V.; Pirisi, F. M. Simplified multiresidue method for the determination of organophosphorus insecticides in olive oil. J. Chromatogr., A 1997, 761, 327-331.
15. Lentza-Rizos, Ch.; Avramides, E. J.; Cherasco, F. Low-temperature cleanup method for the determination of organophosphorus insecticides in olive oil. J. Chromatogr., A 2001, 912, 135-142.
16. Gillespie, A. M.; Daly, S. L.; Gilvydis, D. M.; Schneider, F.; Walters, S. M. Multicolumn Solid-Phase Extraction Cleanup of Organophosphorus and Organochlorine Pesticide Residues in Vegetable Oils and Butterfat. J. AOAC Int. 1995, 78, 431-437.
17. Rastrelli, L.; Totaro, K.; De Simone, F. Determination of organophosphorus pesticide residues in Cilento (Campania, Italy) virgin olive oil by capillary gas chromatography. Food Chem. 2002, 79, 303-305.
18. Di Muccio, A.; Pelosi, P.; Barbini, D. A.; Generali, T.; Girolimenti, S.; Stefanelli, P.; Leonelli, A.; Amendola, G.; Vergori, L.; Fresquet, E. V. Determination of pyrethroid pesticide residues in fatty materials by solid-matrix dispersion partition, followed by mini-column size-exclusion chromatography. J. Chromatogr., A 1997, 833, 19-34.
19. Analytical Methods Commitee of the Royal Society of Chemistry of London. Recomendations for the definition, estimation and use of the detection limit. Analyst 1987, 112, 199-204.
20. Dugo, G.; Di Bella, G.; La Torre, L.; Saitta, M. Rapid GC-FPD determination of organophosphorus pesticide residues in Sicilian and Apulian olive oil. Food Control 2005, 16, 435-438.
21. Cabras, P.; Angioni, A.; Garau, V. L.; Pirisi, F. M.; Cabitza, F.; Pala, M. Acephate and buprofezin residues in olives and olive oil. Food Addit. Contam. 2000, 17, 855-858.
22. Jalón, M.; Urieta, I.; Macho, M. L.; Azpiri, M. Food chemical surveillance in the Basque Country: 1990-1995; Gobierno Vasco: Vitoria, Spain, 1996.
23. Abad, E.; Llerena, J. J.; Saulo, J.; Caixach, J.; Rivera, J. Study on PCDDs/PCDFs and co-PCBs content in food samples from Catalonia (Spain). Chemosphere 2002, 46, 1435-1441.