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Volumn 15, Issue 9, 2004, Pages 1513-1516

A new approach to enantioselective cyanation of imines with Et 2AlCN

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM DERIVATIVE; AMINE; AMINONITRILE; BENZYL DERIVATIVE; CYANIDE; DIETHYLALUMINUM CYANIDE; IMINE; N BENZYLIDENEBENZHYDRYLAMINE; NITRILE; UNCLASSIFIED DRUG;

EID: 2142704287     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetasy.2004.03.040     Document Type: Article
Times cited : (120)

References (56)
  • 2
    • 0000862669 scopus 로고    scopus 로고
    • For reviews of the enantioselective Strecker-type reactions, see:
    • For reviews of the enantioselective Strecker-type reactions, see: Kobayashi S., Ishitani H. Chem. Rev. 99:1999;1069-1094
    • (1999) Chem. Rev. , vol.99 , pp. 1069-1094
    • Kobayashi, S.1    Ishitani, H.2
  • 27
    • 2142776246 scopus 로고    scopus 로고
    • note
    • 2AlCN and a chiral ligand was stirred longer, it took much longer time to complete the cyanation
  • 33
    • 0346122787 scopus 로고    scopus 로고
    • We have recently reported a newly designed chiral ligand having a sulfinyl group:
    • We have recently reported a newly designed chiral ligand having a sulfinyl group: Nakamura S., Fukuzumi T., Toru T. Chirality. 16:2004;10-12
    • (2004) Chirality , vol.16 , pp. 10-12
    • Nakamura, S.1    Fukuzumi, T.2    Toru, T.3
  • 34
    • 2142850744 scopus 로고    scopus 로고
    • note
    • The absolute stereochemistry of 2a was not determined
  • 36
    • 2142834231 scopus 로고    scopus 로고
    • note
    • 2AlCN/ BINOL gave the corresponding cyanated products
  • 51
    • 0031980938 scopus 로고    scopus 로고
    • The dimeric Zr-BINOL complex gives the product having stereochemistry opposite that obtained with the monomeric catalyst:
    • The dimeric Zr-BINOL complex gives the product having stereochemistry opposite that obtained with the monomeric catalyst: Kobayashi S., Komiyama S., Ishitani H. Angew. Chem., Int. Ed. 37:1998;979-981
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 979-981
    • Kobayashi, S.1    Komiyama, S.2    Ishitani, H.3
  • 53
    • 2142670222 scopus 로고    scopus 로고
    • note
    • We observed a negative nonlinear effect in the reaction with BINOL, indicating that the aggregation state of the reactive species should be involved


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.