On the mechanism of cytochrome P450-catalyzed oxidations: Reaction of a new enzyme model with a radical clock

Synthesis

Volumn , Issue 9, 2005, Pages 1538-1542

  Sbaragli, Laura ^a   Woggon, Wolf D ^a  

^a UNIVERSITY OF BASEL   (Switzerland)

Author keywords

Catalysis; Enzyme models; Heme thiolate proteins; Iron porphyrins; Radical clock; Radical rearrangement

Indexed keywords

CATALYSIS; ENZYMES; FREE RADICALS; HYDROGEN BONDS; HYDROXYLATION; METHANOL; MOLECULAR STRUCTURE; PROPANE; REACTION KINETICS;

CYTOCHROME; PRODUCT DISTRIBUTION; RADICAL CLOCK; RADICAL CLUSTERS;

OXIDATION;

1,1 ALLYLPHENYL METHANOL; 2 PHENYL METHYLCYCLOPROPRANE; CYCLOPROPANE DERIVATIVE; CYCLOPROPYL METHANOL; CYTOCHROME P450; IRON; METHANOL DERIVATIVE; SULFATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROGEN BOND; HYDROXYLATION; MODEL; OXIDATION; RADICAL REACTION; REACTION ANALYSIS;

EID: 20644460805     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-865334     Document Type: Article

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