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The N-influence on the gap energy was extracted from experiment. Parameters are similar to Ref. 16. For the band alignment, 36% of the gap difference Δlayer = Eg,GaAs - Eg,layer are attributed to the valence band and 64% to the conduction band. In case of GaNAs, an offset component x Voff, Voff =1.5 eV, is added to the valence band, to account for the influence of the anticrossing.
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