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The temperature at the SAM-water interface was found (via the determination of the second-order rate constant at different surface temperatures and reaction times) to within the experimental error equal to the temperature calibration in air (Figure 1).
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Alternative approaches for the high throughput mapping of gradients have been reported. For example, (a) surface chemistry and molecular orientation using near-edge X-ray absorption fine structure spectroscopy, Fischer, D. A.; Efimenko, K.; Bhat, R. R.; Sambasivan, S.; Genzer, J. Macromol. Rapid Commun. 2004, 25, 141.
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COOH = 15° are the static CAs of the surface composed of NHS ester and carboxyl groups, respectively.
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COOH = 15° are the static CAs of the surface composed of NHS ester and carboxyl groups, respectively.
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