Adsorption and Charge-Transfer Study of Bi-isonicotinic Acid on In Situ-Grown Anatase TiO2 Nanoparticles

Journal of Physical Chemistry B

Volumn 108, Issue 10, 2004, Pages 3114-3122

  Schnadt, Joachim ^a,d   Henningsson, Anders ^a   Andersson, Martin P ^b   Karlsson, Patrik G ^a   Uvdal, Per ^b   Siegbahn, Hans ^a   Brühwiler, Paul A ^a,c   Sandell, Anders ^a  

^a UPPSALA UNIVERSITY   (Sweden)

^b LUND UNIVERSITY   (Sweden)

^c SWISS FEDERAL LABORATORIES FOR MATERIALS SCIENCE AND TECHNOLOGY   (Switzerland)

^d AARHUS UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; BISMUTH; CHARGE TRANSFER; ELECTRIC EXCITATION; NANOSTRUCTURED MATERIALS; ORGANOMETALLICS; PARTICLE BEAM INJECTION; RESONANCE; SPECTROSCOPY; TITANIUM OXIDES; VACUUM; X RAY ANALYSIS;

BONDING GEOMETRY; ELECTRON INJECTION;

ORGANIC ACIDS;

EID: 1842532310     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0344491     Document Type: Article

References (55)

1. Grätzel, M. Prog. Photovoltaics 2000, 8, 171.
2. Hagfeldt, A.; Grätzel, M. Acc. Chem. Res. 2000, 33, 269.
3. Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Müler, E.; Liska, P.: Vlachopoulos, N.: Grätzel, M. J. Am. Chem. Soc. 1993, 115, 6382.
4. Nazeeruddin, M. K.: Pechy, P.; Grätzel, M. Chem. Commun. 1997, 1705.
5. Finnie, K. S.; Bartlett, J. R.; Woolfrey, J. L. Langmuir 1998, 14, 2744.
6. Shklover, V.; Ovchinnikov, Y. E.; Braginsky, L. S.; Zakeeruddin, S. M.; Grätzel, M. Chem. Mater. 1998, 10, 2533.
7. Rensmo, H.; Westermark, K.; Södergren, S.; Kohle, O.: Persson, P.; Lunell, S.; Siegbahn, H. J. Chem. Phys. 1999, 111, 2744.
8. Fillinger, A.; Parkinson, B. A. J. Electrochem. Soc. 1999, 146, 4559.
9. Persson, P.; Lunell, S. Sol. Energy Mater. Sol. Cells 2000, 63, 139-148.
10. Patthey, L.: Rensmo, H.; Persson, P.: Westermark, K.; Vayssieres, L.; Stashans, A.; Petersson, Å.; Brühwiler, P. A.; Siegbahn, H.; Lunell, S.; Mårtensson, N. J. Chem. Phys. 1999, 110, 5913.
11. Schnadt, J.; Brühwiler, P. A.; Patthey, L.; O'Shea, J. N.; Södergren, S.; Odelius, M.; Ahuja, R.; Karis, O.; Bässler, M.; Persson, P.; Siegbahn, H.; Lunell, S.; Mårtensson, N. Nature 2002, 418, 620.
12. Sandell, A.; Andersson, M. P.; Alfredsson, Y.; Johansson, M. K.-J.: Schnadt, J.; Rensmo, H.; Siegbahn, H.; Uvdal, P. J. Appl. Phys. 2002, 92, 3381.
13. O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.
14. Brühwiler, P. A.; Karis, O.; Mårtensson, N. Rev. Mod. Phys. 2002, 74, 703.
15. Westermark, K.; Rensmo, H.; Schnadt, J.; Persson, P.; Södergren, S.; Brühwiler, P. A.; Lunell, S.; Siegbahn, H. Chem. Phys. 2002, 285, 167.
16. Andersen, J. N.; Björneholm, O.; Sandell, A.; Nyholm, R.; Forsell, J.; Thånell, L.; Nilsson, A.; Mårtensson, N. Synchrotron Radiat. News 1991, 4 (4), 15.
17. Nyholm, R.; Svensson, S.; Nordgren, J.; Flodström, A. Nucl. Instrum. Methods A 1986, 246, 267.
18. Maxwell, A. J.; Brühwiler, P. A.; Arvanitis, D.; Hasselström. J.; Mårtensson, N. Chem. Phys. Lett. 1996, 260, 71.
19. Schnadt, J.; O'Shea, J. N.; Patthey, L.; Krempaský, J.; Mårtensson, N.; Brühwiler, P. A. Phys. Rev. B. 2003, 67, 235420.
20. Coville, M.; Thomas, T. D. Phys. Rev. A 1991, 43, 6053.
21. Persson, P.: Stashans, A.; Bergström, R.; Lunell, S. Int. J. Quantum Chem. 1998, 70, 1055.
22. Lazzeri, M.; Vittadini, A.; Selloni, A. Phys. Rev. B 2001, 63, 155409.
23. Lazzeri, M.; Vittadini, A.; Selloni, A. Phys. Rev. B 2002, 65, 119901.
24. Hebenstreit, W.; Ruzycki, N.; Herman, G. S.; Gao, Y.; Diebold, U. Phys. Rev. B 2000, 64, R16334.
25. Hengerer, R.; Bolliger, B.; Erbudak, M.; Grätzel, M. Surf. Sci. 2000, 460, 162.
26. Burnside, S. D.; Shklover, V.; Barbé, C.; Comte, P.; Arendse, F.; Brooks, K.; Grätzel, M. Chem. Mater. 1998, 10, 2419.
27. Persson, P.; Lunell, S.; Brühwiler, P. A.; Schnadt, J.; Södergren, S.; O'Shea, J. N.; Karis, O.; Siegbahn, H.; Mårtensson, N.; Bässler, M.; Patthey, L. J. Chem. Phys. 2000, 112, 3945.
28. In photoemission spectroscopy, shake-up structures appear as features at higher binding energies (and, hence, lower kinetic energies) than the main peaks, typically with a separation of a few tenths of an electron volt to several or some tens of electron volts from the main peak. They are a result of multielectron processes in which electrons are excited from the occupied valence orbitals to the unoccupied ones, thereby reducing the kinetic energy of the outgoing (and measured) photoelectron (cf. panel c in Figure 5 in this paper). An analysis of their energies and intensities can provide useful information, in particular, about the electronic structure and the screening properties of the probed system (see, for example, refs 29-31).
29. Hüfner, S. Photoelectron Spectroscopy, 2nd ed.; Springer-Verlag: Berlin, 1996.
30. Enkvist, C.; Lunell, S.: Svensson, S. Chem. Phys. 1997, 214, 123.
31. Tillborg, H.; Nilsson, A.; Mårtensson, N. J. Electron Spectrosc. Relat. Phenom. 1993, 62, 73.
32. Schnadt, J.: O'Shea, J. N.; Patthey, L.; Schliessung, J.: Krempaský, J.; Shi, M.; Mårtensson, N.; Brühwiler, P. A. Surf. Sci. 2003, 544, 74.
33. 38 Although the present knowledge is not sufficient for a quantitative evaluation of the substrate screening responses, it can be noted that the intramolecular charge-transfer character of the shakeup will lead to different responses for the shake-up final state and the main line, and that these, generally, are different for the different substrates. The explanation is also consistent with the XAS result that the Orbitals are quite similar for the two cases.
34. Durand, E. Electrostatique. Tome III. Méthodes de Calcul Diélectriques; Masson et Cie: Paris, 1966; pp 232-233.
35. Chiang, T.-C.; Kaindl, G.; Mandel, T. Phys. Rev. B 1986, 33, 695.
36. Parker, R. A. Phys. Rev. 1961, 124, 1719.
37. Park, B. H.; Li, L. S.; Gibbons, B. J.; Huang, J. Y.; Jia, Q. X. Appl. Phys. Lett. 2001, 79, 2797.
38. Fukuda, H.; Namioka, S.; Miura, M.; Ishikawa, Y.; Yoshino, M.; Nomura, S. Jpn. J. Appl. Phys. 1999, 38, 6034.
39. C = 6 fs, which is the mean value of the numbers given previously.
40. Schnadt, J.; O'Shea, J. N.; Patthey, L.; Kjeldgaard, L.; Åhlund, J.; Nilson, K.; Schiessling, J.; Krempaský, J.; Shi, M.; Karis, O.; Glover, C.; Siegbahn, H.: Mårtensson, N.; Brühwiler, P. A. J. Chem. Phys. 2003, 119, 12462.
41. For an isolated excited state, the RPES signal disperses linearly on the binding energy scale, by virtue of energy conservation, if the experiment is conducted using narrow-band excitation, i.e., using a photon resolution below the lifetime broadening of the excited state (see, for example, ref 14). The experiment is said to be conducted under Auger resonant Raman (ARR) conditions. Even then, the overall dispersion across the entire spectral range is zero for two or more energetically well-separated excited (electronic) states (not coupled to any continuum), whereas it is linear within each resonance. Finally, for excited states with overlapping tails (commonly vibrational states), interference effects that destroy the linear dispersion might be present (see, for example, ref 42). In principle, the present experiment could be conducted using both narrow-band or broad-band excitation, and, in both cases, the overall zero dispersion can be used to distinguish RPES and RAES features, because several well-separated electronic resonances are part of the experiment's spectral range.
42. Piancastelli, M. N. J. Electron Spectrosc. Relat. Phenom. 2000, 107, 1.
43. A normalization using a gas-phase measurement truly representing the isolated molecule would be ideal but, however, is not easily conducted, because of the low vapor pressure of BINA.
44. Persson, P.; Lunell, S.; Ojamäe, L. Chem. Phys. Lett. 2002, 364, 469.
45. Odelius, M.; Persson, P.; Lunell, S. Surf. Sci. 2003, 529, 47.
46. Wurth, W.; Menzel, D. Chem. Phys. 2000, 251, 141.
47. See, e.g., ref 50.
48. Menzel, D.; Rocker, G.; Steinrück, H.-P.; Coulman, D.; Heimann, P. A.; Huber, W.; Zebisch, P.; Lloyd, D. R. J. Chem. Phys. 1992, 96, 1724.
49. Mauerer, M.; Zebisch, P.; Weinelt, M.; Steinrück, H.-P. J. Chem. Phys. 1993, 99, 3343.
50. Dudde, R.; Rocco, M. L. M.; Koch, E. E.; Bernstorff, S.; Eberhardt, W. J. Chem. Phys. 1989, 91, 20.
51. 40 The present curve has been extracted from these data.
52. Brühwiler, P. A.; Maxwell, A. J.; Mårtensson, N. Int. J. Mod. Phys. B 1992, 6, 3923.
53. Stier, W.; Prezhdo, O. V. J. Phys. Chem. B 2002, 106, 8047.
54. Schnadt, J.; Schiessling, J.; Brühwiler, P. A. submitted to Phys. Rev. B.
55. Lanzafame, J. M.; Palese, S.; Wang, D.; Miller, R. J. D.; Muenter, A. A. J. Phys. Chem. 1994, 98, 11020.