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Volumn 108, Issue 10, 2004, Pages 1764-1778

A Theory of Intervalence Band Stark Effects

Author keywords

[No Author keywords available]

Indexed keywords

INTERVALENCE BANDS; STARK SPECTROSCOPY;

EID: 1842531455     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp035890u     Document Type: Article
Times cited : (34)

References (48)
  • 2
    • 1842525509 scopus 로고    scopus 로고
    • note
    • 1/2; (iii) if a symbol such as Δv̄ is used as both Δv̄ and Δv̄(F), then Δv̄ alone refers to the F-independent component of Δv̄(F).
  • 6
    • 1842578013 scopus 로고    scopus 로고
    • Treynor, T. P.; Boxer, S. G. Manuscript in preparation
    • Treynor, T. P.; Boxer, S. G. Manuscript in preparation.
  • 7
    • 0003740824 scopus 로고
    • Electric Field Perturbation of Electronic (Vibronic) Absorption Envelopes: Application to Characterization of Mixed Valence States
    • ed.; Prassides, K., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands
    • Reimers, J. R.; Hush, N. S. Electric Field Perturbation of Electronic (Vibronic) Absorption Envelopes: Application to Characterization of Mixed Valence States. In Proceedings of the NATO Advanced Workshop on Mixed Valency Compounds: applications in Chemistry, Physics and Biology; Series C ed.; Prassides, K., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1990.
    • (1990) Proceedings of the NATO Advanced Workshop on Mixed Valency Compounds: Applications in Chemistry, Physics and Biology; Series C
    • Reimers, J.R.1    Hush, N.S.2
  • 11
    • 1842473399 scopus 로고    scopus 로고
    • note
    • As we have noted, eqs 4-7 were also derived with the assumption that the field-perturbations to the individual transitions are small compared to their line widths and intensities. We do not consider violations of these assumptions to yield nonclassical Stark effects because eqs 4-7 continue to apply so long as the Stark spectrum is fit to a sum of the zeroth-, first-, and second-order and higher order v̄-weighted derivatives of the absorption spectrum. This behavior is readily derived from the other assumptions of the classical Stark analysis.
  • 17
    • 1842578012 scopus 로고    scopus 로고
    • note
    • A field-independent inhomogeneous broadening line width can be added at this level of the analysis.
  • 18
    • 0041878862 scopus 로고    scopus 로고
    • While we have been editing this manuscript, Reimers and Hush have submitted for publication a manuscript that defines the same vibronic coupling model with regard to the coupling between the ground and hole-transferred states of the special pair radical cation [Reimers, J. R.; Hush, N. S. J. Chem. Phys. 2003, 3262.]. In response to our manuscript they have also authored an erratum attesting that the equation in ref 20, which is represented here as eq 13, is in error [Reimers, J. R.; Hush, N. S. Personal communication].
    • (2003) J. Chem. Phys. , pp. 3262
    • Reimers, J.R.1    Hush, N.S.2
  • 19
    • 1842525508 scopus 로고    scopus 로고
    • Personal communication
    • While we have been editing this manuscript, Reimers and Hush have submitted for publication a manuscript that defines the same vibronic coupling model with regard to the coupling between the ground and hole-transferred states of the special pair radical cation [Reimers, J. R.; Hush, N. S. J. Chem. Phys. 2003, 3262.]. In response to our manuscript they have also authored an erratum attesting that the equation in ref 20, which is represented here as eq 13, is in error [Reimers, J. R.; Hush, N. S. Personal communication].
    • Reimers, J.R.1    Hush, N.S.2
  • 24
    • 1842473398 scopus 로고    scopus 로고
    • Ph.D. Thesis, Stanford University
    • Treynor, T. P. Ph.D. Thesis 2003, Stanford University.
    • (2003)
    • Treynor, T.P.1
  • 27
    • 1842578006 scopus 로고    scopus 로고
    • note
    • 2 surfaces are equal; this translation of the origin simplifies the comparison of the GSB treatment with the RH treatment discussed below.
  • 35
    • 1842578005 scopus 로고    scopus 로고
    • Personal communication
    • Reimers, J. R. Personal communication.
    • Reimers, J.R.1
  • 37
  • 38
    • 0142072231 scopus 로고    scopus 로고
    • Andrews, S. S.; Boxer, S. G. J. Phys. Chem. A 2000, 104, 11853. Suydam, I. T.; Boxer, S. G. Biochemistry 2003, 42, 12050.
    • (2003) Biochemistry , vol.42 , pp. 12050
    • Suydam, I.T.1    Boxer, S.G.2
  • 44
    • 1842420909 scopus 로고    scopus 로고
    • Treynor, T. P.; Lee, C.-I.; Brudvig, G.; Boxer, S. G. Manuscript in preparation
    • Treynor, T. P.; Lee, C.-I.; Brudvig, G.; Boxer, S. G. Manuscript in preparation.
  • 47
    • 1842578008 scopus 로고    scopus 로고
    • note
    • -1 for MVC 7 has been removed from Figure 8 because the inhomogeneities in Δv̄ found in condensed phases are likely to destroy nearly all of its intensity.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.