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Volumn 100, Issue 20, 1996, Pages 8157-8169

Electroabsorption spectroscopy of charge-transfer states of transition-metal complexes. 2. Metal-to-ligand and ligand-to-metal charge-transfer excited states of pentaammineruthenium complexes

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CHARGE TRANSFER; ELECTRON ENERGY LEVELS; MATHEMATICAL MODELS; TRANSITION METAL COMPOUNDS;

EID: 0030134513     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp953395v     Document Type: Article
Times cited : (144)

References (55)
  • 1
    • 33748566673 scopus 로고    scopus 로고
    • Part 1 is ref 23
    • Part 1 is ref 23.
  • 27
    • 33748579166 scopus 로고
    • Ph.D. Thesis, Stanford University, June
    • Oh, D. H. Ph.D. Thesis, Stanford University, June, 1991.
    • (1991)
    • Oh, D.H.1
  • 28
    • 85086528010 scopus 로고    scopus 로고
    • note
    • 2 are the refractive indexes of the sample glass (1.4) and liquid nitrogen (1.2), respectively.
  • 30
    • 0001269334 scopus 로고
    • Lim, E. C., Ed.; Academic Press: New York
    • Liptay, W. In Excited States; Lim, E. C., Ed.; Academic Press: New York, 1974; Vol. 1, pp 129-229.
    • (1974) Excited States , vol.1 , pp. 129-229
    • Liptay, W.1
  • 31
    • 0002044591 scopus 로고
    • Rossiter, B. W., Hamilton, J. F., Eds.; Wiley: New York
    • Baumann, W. In Physical Methods of Chemistry; Rossiter, B. W., Hamilton, J. F., Eds.; Wiley: New York, 1989; Vol. IIIB, pp 45-131.
    • (1989) Physical Methods of Chemistry , vol.3 B , pp. 45-131
    • Baumann, W.1
  • 44
    • 85086527094 scopus 로고    scopus 로고
    • note
    • ge is a vector with x, y, and z spatial components. It is often necessary to sum over either the spatial components or the states. When the sum is over the spatial components, a subscript i, j, or k is used, while r or s is used for the sum over states. Note that state quantities are denoted by a single subscript g or e and transition quantities by a double subscript.
  • 50
    • 85086527662 scopus 로고    scopus 로고
    • note
    • +, with the added proton placed 2.0 Å from the ligating nitrogen to simulate the effect of the charge of the Ru(II) center. For the INDO calculations the proton was removed and replaced by the appropriate charge (2+ or 3+) to simulate the metal center.
  • 52
    • 33748577855 scopus 로고    scopus 로고
    • note
    • Equation 1a of ref 23 contains a typographical error; the equation should be identical with eq 40a of this paper. The correct equation was used in the calculations reported in ref 23.
  • 53
    • 33748518752 scopus 로고    scopus 로고
    • note
    • 3. Furthermore, the last two terms are relatively small and tend to cancel.
  • 55
    • 85086526734 scopus 로고    scopus 로고
    • note
    • 0.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.