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17144392313
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note
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- counterions, respectively. In cases where only one of the two salts was prepared, a and b are omitted.
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17144413501
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note
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Similar pairs are observed for coordinated propylene, though the rotation cannot be completely frozen out in this case.
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13
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0037190102
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17
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17144364801
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note
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‡ values of 15.6 and 15.9 kcal/mol, respectively.
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18
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11344284526
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follows p 1914
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Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R. J. Chem. Soc., Perkin Trans. 2 1987, S1-S19 (follows p 1914).
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19
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14344283641
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McCord, E. F.; McLain, S. J.; Nelson, L. T. J.; Arthur, S. D.; Coughlin E. B.; Ittel, S. D.; Johnson, L. K.; Tempel, D.; Killian, C. M.; Brookhart, M. Macromolecules 2001, 34, 362.
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20
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17144408108
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note
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Because ethylene distribution between the headspace and solution varied with temperature, ethylene concentration at a given temperature was determined by NMR integration.
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21
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17144423375
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note
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3CN may organize the solvent more extensively than free ethylene.
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22
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17144388004
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note
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f group to a the beta or gamma position and generates a species with a much lower barrier to insertion. From observations summarized in Scheme 6, this method for insertion from 18 appears feasible, but the beta and gamma species are clearly higher in energy and the overall effect would still be a much higher apparent barrier of 18.
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23
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17144414262
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note
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25 more electron rich olefins inserted more rapidly. In the first and third cases, the overall rates measured were a combination of both a binding constant and an insertion rate.
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27
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31
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17144381413
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note
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It should be noted that 19 contains 2.6-diisopropylphenyl groups on the diimine, while the diimine aryls of 4 are 2,6-dimethylphenyl. Typically, differences between rates and equilibria of palladium complexes of varying diimine ligands are small, being on the order of a kcal/mol or less.
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32
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17144429848
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34 and MeLi as per the procedure reported for the synthesis of the analogous Pd complex with 2,6-diisopropyl groups attached to the nitrogen ligand in ref 2.
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