13C and 2D NMR analysis of propylene polymers made with a-diimine late metal catalysts

Macromolecules

Volumn 34, Issue 3, 2001, Pages 362-371

  McCord, E F ^a,b   McLain, S J ^a   Nelson, L T J ^a   Arthur, S D ^a   Coughlin, E B ^a   Ittel, S D ^a   Johnson, L K ^a   Tempel, D ^a   Killian, C M ^a   Brookhart, M ^a  

^a DUPONT COMPANY   (United States)

^b University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COPOLYMERIZATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYOLEFINS; TRANSITION METALS;

LATE METAL CATALYSTS;

POLYPROPYLENES;

EID: 14344283641     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0012898     Document Type: Article

References (53)

1. See, for instance: (a) Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem. Rev. 2000, 700, 1169-1204.
2. (b) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. Engl. 1999, 38, 428.
3. (c) Johnson, L. K.; Killian, C. M. In Metallocene-Based Polyolefins, Preparation, Properties and Technology; Scheirs, J., Kaminsky, W., Eds.; Wiley: West Sussex, England, 2000; p 233.
4. (d) Ittel, S. D. In Metalorganic Catalysts for Synthesis and Polymerization; Kaminsky, W., Ed.; Springer-Verlag: Heidelberg, 1999; P 616.
5. Johnson, L. K.; Killian, G M Brookhart, M. J. Am. Chem. Soc. 1995, 117, 6414.
6. Johnson, L. K; Killian, C. M.; Arthur, S. D.; Feldman, J.; McCord, E. F.; McLain, S. J.; Kreutzer, K. A.; Bennett, A. M. A.; Coughlin, E. B.; Ittel, S D.; Parathasarathy, A.; Tempel, D. J.; Brookhart, M. S Pat. Appl. WO 9623010 to DuPont, Äug l, 1996.
7. See for instance: Razavi, A.; Atwood, J. L. J. Organomet. Chem. 1995,497 (1-2), 105-11,
8. or Dolle, V.; Rohrmann, J.; Winter, A.; Antberg, M.; Klein, R. Eur. Pat. Appl., EP 399347 to Hoechst A.-G, Priority date Nov 28,1990, for examples of isotactic/syndiotactic block polymers.
9. See: Ewen, J. A. Eur. Pat. Appl., EP 423101 to Fina Technology, Priority date April 17, 1991, for examples of hemi-isotactic polymers.
10. (a) Natta, G.; Pino, P.; Massanti, G.; Natta, G.; Pino, P.; Massanti, G. Ital. Pat. 535,712 to Montacatini, 1954.
11. (b) Natta, G. J. Am. Chem. Soc. 1955, 77, 1708.
12. Ewen, J. A. J. Am. Chem. Soc. 1984, 706, 6355.
13. For a review, see: Brintzinger, H. H.; Fischer, D.; Mulhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
14. See for instance: Rieger, B.; Reinmuth, A.; Roell, W.; Brintzinger, H: H. J. Mol. Catal. 1993, 82, 67-73.
15. Ewen, J. A.; Jones, R. L.; Razavi, A.; Ferrara, J. D. J. Am. Chem. Soc. 1988, 110, 6255-6256.
16. Zambelli, A.; Locatelli, P.; Provasoli, A.; Ferro, D. R. Macromolecules 1980, 13, 267.
17. Zambelli, A.; Locatelli, P.; Zannoni, G.; Bovey, F. A. Macromolecules 1978, 11, 923.
18. Ewen, J. A. J. Am. Chem. Soc. 1984, 106, 6355-64.
19. Spaleck, W.; Anthberg, M.; Aulbach, M.; Bachmann, B.; Dolle, V.; Haftka, S.; Keuber, F.; Rohrmann, J.; Winter, A. In Ziegler Catalysts; Fink, G., Mulhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Heidelberg, 1995; pp 83-97.
20. Zambelli, A.; Bajo, G.; Rigamonti, E. Makromol. Chem. 1978, 179, 1249.
21. (a) Kravchenko, R.; Masood, A.; Waymouth, R. M.; Myers, C. L. J. Am. Chem. Soc. 1998, 120, 2039-2046.
22. (b) Bruce, M. D.; Coates, G. W.; Hauptman, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 11174-11182.
23. (c) Hauptman, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1995, 117, 11586-7.
24. Bovey, F. A.; Tiens, G. V. D. J. Polym. Sei. 1960, 44, 173.
25. Sheldon, R. A.; Fueno, T.; Tsunetsuga, T.; Furukawa, J. J. Polym. Sei., Part A: Polym. Chem. 1965, 3, 23.
26. Asakura, T.; Nakayama, N.; Demura, M.; Asano, A. Macromolecules 1992, 25, 4876.
27. Schilling, F. C.; Tonelli, A. E. Macromolecules 1980,13, 270.
28. Randall, J. C. Polymer Sequence Determination: Carbon-13 NMR Method; Academic Press: New York, 1978.
29. Zambelli, A.; Locatelli, P.; Bajo, G.; Bovey, F. A. Macromolecules 1975, 8, 687.
30. Tritto, L; Fan, Z. Q.; Locatelli, P.; Sacchi, M. C.; Camurati, L; Galimberti, M. Macromolecules 1995, 28, 3342.
31. Cheng, H. N.; Smith, D. A. Macromolecules 1986, 19, 2065.
32. Cheng, H. N. Macromolecules 1984, 17, 1950.
33. Doi, Y. Makromol. Chem., Rapid Commun. 1981, 2, 293.
34. Wolfsgruber, C.; Zannoni, G.; Rigamonti, E.; Zambelli, A. Makromol. Chem. 1975, 176, 2765.
35. Dahlmann, M.; Erker, G.; Nissinen, M.; Froehlich, R. J. Am. Chem. Soc. 1999, 121, 2820-2828.
36. Zambelli, A.; Locatelli, P.; Rigamonti, E. Macromolecules 1979, 12, 156.
37. Grassi, A.; Zambelli, A.; Resconi, L.; Albizzati, E.; Mazzocchi, R. Macromolecules 1988, 21, 617.
38. Busico, V.; Cipullo, R. Macromol. Symp. 1995, 89, 277.
39. Dolle, V.; Rohrmann, J.; Winter, A.; Antberg, M.; Klein, R. German Patent Appl. DE 3826075 to Hoechst Aktiengesellischraft, Feb l, 1990.
40. Yuguchi, S.; Iwamoto, M. Polym. Lett. 1964, 2, 1035.
41. Ketley, A. D.; Braatz, J. A. Polym. Lett. 1968, 6, 341.
42. Busico, V.; Cipullo, R.; Monaco, G.; Vacatello, M. S.; Anna, L. Macromolecules 1997, 30, 6251.
43. Soga, K.; Shiono, T.; Takemura, S.; Kaminsky, W. Makromol. Chem., Rapid Commun. 1987, 8, 305.
44. Svejda, S. A.; Johnson, L. K.; Brookhart, M. J. Am. Chem. Soc. 1999, 121, 10634.
45. Pellecchia, C.; Zambelli, A. Makromol. Chem., Rapid Commun. 1996, 17, 333.
46. Pellecchia, C.; Zambolli, A.; Olivia, L.; Pappalardo, D. Macromolecules 1996, 29, 6990.
47. Pellecchia, C.; Zambelli, A.; Mazzeo, M.; Pappalardo, D. J. Mol. Catal. A: Chem. 1998, 128, 229.
48. Hayashi, T.; Inoue, Y.; Chujo, R.; Asakura, T. Polym. J. 1988, 20, 895.
49. Hikichi, K.; Hiraoki, T.; Ikura, M.; Higuchi, K.; Eguchi, K Ohuchi, M. Polym. J. 1987, 19, 1317.
50. Bax, A.; Freeman, R. J. Magn. Reson. 1980, 41, 507.
51. Cheng, H. N.; Ewen, J. A. Makromol. Chem. 1989,190,1931.
52. Asakura, T.; Nishiyama, Y.; Do:, Y. Macromolecules 1987, 20, 616.
53. Cheng, H. N. Polym. Bull. (Berlin) 1985,14, 347.