Enantioselective total synthesis of polyoxygenated cyclohexanoids: (+)-streptol, ent-RKTS-33 and putative '(+)-parasitenone'. Identity of parasitenone with (+)-epoxydon

Tetrahedron Letters

Volumn 46, Issue 19, 2005, Pages 3373-3376

  Mehta, Goverdhan ^a   Pujar, Shashikant R ^a   Ramesh, Senaiar S ^a   Islam, Kabirul ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

APOPTOSIS INHIBITOR; CYCLOHEXANE DERIVATIVE; EPOXYDONE; NATURAL PRODUCT; PARASITENONE; PEPTIDE; RKTS 33; STREPTOL; UNCLASSIFIED DRUG;

ARTICLE; CHIRALITY; CONTROLLED STUDY; DRUG STRUCTURE; DRUG SYNTHESIS; ENANTIOSELECTIVITY; NONHUMAN; OXYGENATION;

EID: 17144393269     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.03.087     Document Type: Article

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39. 6) of natural 'parasitenone',10 synthetic 12 and (+)-epoxydon 3a
40. -1. Total number of l.s. parameters = 201, R1 = 0.050 for 1747 Fo > 4 sig (Fo) and 0.062 for all 2089 data. wR2 = 0.105, GOF = 1.116, restrained GOF = 1.116 for all data. Crystallographic data have been deposited with the Cambridge Crystallographic Data Centre, UK (CCDC 260720). An ORTEP diagram (with 50% ellipsoidal probability) is shown below