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Volumn 8, Issue 7, 2002, Pages 1741-1752

Bonding and redox properties of [Os3(CO)9(tmbp)(L)] (tmbp = 4,4′,5,5′-tetramethyl-2,2′-biphosphinine; L = CO, PPh3) clusters with an unprecedented electron-deficient metallic core and doubly bridging biphosphinine dianion

(7) Bakker, Maarten J a Vergeer, Frank W a Hartl, František a Rosa, Patrick b Ricard, Louis b Le Floch, Pascal b Calhorda, Maria J c

a UNIVERSITY OF AMSTERDAM (Netherlands)

b LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION (France)

c INSTITUTO DE TECNOLOGIA QUÍMICA E BIOLÓGICA (Portugal)

Author keywords

Cluster compounds; Density functional calculations; Osmium; P ligands; Spectroelectrochemistry; X ray diffraction

Indexed keywords

CHEMICAL BONDS; CRYSTAL STRUCTURE; DISSOCIATION; INFRARED SPECTROSCOPY; ISOMERS; NEGATIVE IONS; REDOX REACTIONS; REDUCTION; SUBSTITUTION REACTIONS;

CHEMICAL CLUSTERS;

ELECTROCHEMISTRY;

4,4',5,5' TETRAMETHYL 2,2' BISPHOSPHININE; BISPHOSPHONIC ACID DERIVATIVE; OSMIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CLUSTER ANALYSIS; CRYSTAL STRUCTURE; CYCLIC POTENTIOMETRY; DISSOCIATION; ELECTROCHEMICAL ANALYSIS; ELECTRON TRANSPORT; HYDROGEN BOND; ISOMERISM; LOW TEMPERATURE PROCEDURES; OXIDATION REDUCTION REACTION; PHASE TRANSITION; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

EID: 0037006829 PISSN: 09476539 EISSN: None Source Type: Journal
DOI: 10.1002/1521-3765(20020402)8:7<1741::AID-CHEM1741>3.0.CO;2-Z Document Type: Article

Times cited : (23)

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